dioxygenbis(triphenylphosphine)platinum⁽⁰⁾

Base Information

• Chemical Name: dioxygenbis(triphenylphosphine)platinum⁽⁰⁾
• CAS No.: 29894-57-3
• Molecular Formula: C₃₆H₃₀O₂P₂Pt
• Molecular Weight: 751.661
• Mol file: 29894-57-3.mol

Synonyms:dioxygenbis(triphenylphosphine)platinum⁽⁰⁾

Chemical Property of dioxygenbis(triphenylphosphine)platinum⁽⁰⁾

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of dioxygenbis(triphenylphosphine)platinum⁽⁰⁾

There total 3 articles about dioxygenbis(triphenylphosphine)platinum⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1) → bis(triphenylphosphine)carbonateplatinum(II) (17030-86-3) + (PPh3)2Pt(O2) (29894-57-3) + Triphenylphosphine oxide (791-28-6)

Guidance literature:

With carbon dioxide; oxygen; In acetonitrile; benzene; Electrolysis; a MeCN-benzene soln. of Pt-complex was electrolyzed at -1.60 V vs. Ag/AgCl under Ar (Hg working electrode, Pt wire counterelectrode, n-Bu4ClO4, suspended activated Al2O3, two-electron reduction) followed by exposure to air; products were identified in soln. by (31)P NMR spectroscopy;

DOI:10.1021/om00137a038

Reference yield:

Pt(P(C6H5)3)2(OOH)(HCONC6H5) (102982-51-4) → dioxygenbis(triphenylphosphine)platinum(0) (29894-57-3) + Formanilid (103-70-8)

Guidance literature:

In not given; N2-atmosphere, CHCl3/Hexane or ethanol/hexane;

DOI:10.1016/0022-328X(85)80356-9

Reference yield:

tetrakis{tri(2-pyridyl)phosphine}platinum(0) (137507-02-9) → dioxygenbis(triphenylphosphine)platinum(0) (29894-57-3)

Guidance literature:

With oxygen; In dichloromethane; 20°C;

DOI:10.1016/0022-328X(91)80178-M

upstream raw materials:

cis-dichlorobis(triphenylphosphine)platinum(II)

tetrakis{tri(2-pyridyl)phosphine}platinum⁽⁰⁾

Pt(P(C₆H₅)3)2(OOH)(HCONC₆H₅)

Downstream raw materials:

((C₆H₅)3P)2PtOC(CH₃)(C₂H₅)OO

(hydroperoxo)(phthalimido)bis(triphenylphosphino) platinum(II)

Pt(P(C₆H₅)3)2(O₂C(CH₂CO₂CH₃)2O)

Pt(P(C₆H₅)3)2(NC(O)CH₂CH₂CO)2

Refernces

• 1、 Davies, Julian A.,Eagle, Cassandra T.,Otis, Deborah E.,Venkataraman, Uma. "Electrochemical generation and reactivity of bis(triphenylphosphine)platinum(0): An electrosynthesis of platinum-acetylene complexes". . p. 1264 - 1266. Retrieved 2008/10/08.