γ-benzoyloxy-2,4-di(2-chloroethyl)-6,7-di(2-methoxycarbonylethyl)-1,3,5,8-tetramethylporphyrin

Base Information

Chemical Name:γ-benzoyloxy-2,4-di(2-chloroethyl)-6,7-di(2-methoxycarbonylethyl)-1,3,5,8-tetramethylporphyrin
CAS No.:79760-31-9
Molecular Formula:C₄₃H₄₄Cl₂N₄O₆
Molecular Weight:783.752
Hs Code.:

Synonyms:γ-benzoyloxy-2,4-di(2-chloroethyl)-6,7-di(2-methoxycarbonylethyl)-1,3,5,8-tetramethylporphyrin

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of γ-benzoyloxy-2,4-di(2-chloroethyl)-6,7-di(2-methoxycarbonylethyl)-1,3,5,8-tetramethylporphyrin

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of γ-benzoyloxy-2,4-di(2-chloroethyl)-6,7-di(2-methoxycarbonylethyl)-1,3,5,8-tetramethylporphyrin

There total 14 articles about γ-benzoyloxy-2,4-di(2-chloroethyl)-6,7-di(2-methoxycarbonylethyl)-1,3,5,8-tetramethylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 79760-30-8
Benzoic acid (5E,10Z,14Z,19Z)-13,18-bis-(2-hydroxy-ethyl)-3,7-bis-(2-methoxycarbonyl-ethyl)-2,8,12,17-tetramethyl-porphyrin-5-yl ester

: 79760-31-9
γ-benzoyloxy-2,4-di(2-chloroethyl)-6,7-di(2-methoxycarbonylethyl)-1,3,5,8-tetramethylporphyrin

Guidance literature:: With thionyl chloride; potassium carbonate; In chloroform; N,N-dimethyl-formamide; for 2h;
DOI:10.1016/S0040-4020(01)88698-1

Reference yield:

: 4792-10-3
3-{5-Formyl-2-[5-formyl-3-(2-methoxycarbonyl-ethyl)-4-methyl-1H-pyrrol-2-ylmethyl]-4-methyl-1H-pyrrol-3-yl}-propionic acid methyl ester

: 79760-31-9
γ-benzoyloxy-2,4-di(2-chloroethyl)-6,7-di(2-methoxycarbonylethyl)-1,3,5,8-tetramethylporphyrin

Guidance literature:: Multi-step reaction with 5 steps

1: SO₂Cl₂

2: 48 percent / TFA / 2 h / 20 °C

3: pyridine

4: acid / methanol

5: SOCl₂ / dimethylformamide

With thionyl chloride; sulfuryl dichloride; trifluoroacetic acid; In pyridine; methanol; N,N-dimethyl-formamide;
DOI:10.1039/c39810000763

Reference yield:

: 75630-46-5
benzyl 5-acetoxymethyl-3-(methoxycarbonylmethyl)-4-methylpyrrole-2-carboxylate

: 79760-31-9
γ-benzoyloxy-2,4-di(2-chloroethyl)-6,7-di(2-methoxycarbonylethyl)-1,3,5,8-tetramethylporphyrin

Guidance literature:: Multi-step reaction with 8 steps

1: 81 percent / SnCl₄ / CH₂Cl₂ / 1.5 h / -10 - 0 °C

2: 90 percent / diborane / tetrahydrofuran / 4.5 h

3: 90 percent / pyridine / 2 h / Ambient temperature

4: H₂, Et₃N / 10percent Pd-C / methanol / 20 °C / 760 Torr

5: trifluoroacetic acid / 2 h

6: pyridine / 0.5 h

7: 96 percent / 5percent H₂SO₄ / methanol / 1 h / Heating

8: 72 percent / K₂CO₃, SOCl₂ / CHCl₃; dimethylformamide / 2 h

With thionyl chloride; sulfuric acid; hydrogen; tin(IV) chloride; potassium carbonate; triethylamine; trifluoroacetic acid; diborane; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; dichloromethane; chloroform; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)88698-1