Benzoic acid (5E,10Z,14Z,19Z)-13,18-bis-(2-hydroxy-ethyl)-3,7-bis-(2-methoxycarbonyl-ethyl)-2,8,12,17-tetramethyl-porphyrin-5-yl ester

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Chemical Name:Benzoic acid (5E,10Z,14Z,19Z)-13,18-bis-(2-hydroxy-ethyl)-3,7-bis-(2-methoxycarbonyl-ethyl)-2,8,12,17-tetramethyl-porphyrin-5-yl ester
CAS No.:79760-30-8
Molecular Formula:C₄₃H₄₆N₄O₈
Molecular Weight:746.86
Hs Code.:

Synonyms:Benzoic acid (5E,10Z,14Z,19Z)-13,18-bis-(2-hydroxy-ethyl)-3,7-bis-(2-methoxycarbonyl-ethyl)-2,8,12,17-tetramethyl-porphyrin-5-yl ester

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Chemical Property of Benzoic acid (5E,10Z,14Z,19Z)-13,18-bis-(2-hydroxy-ethyl)-3,7-bis-(2-methoxycarbonyl-ethyl)-2,8,12,17-tetramethyl-porphyrin-5-yl ester

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Technology Process of Benzoic acid (5E,10Z,14Z,19Z)-13,18-bis-(2-hydroxy-ethyl)-3,7-bis-(2-methoxycarbonyl-ethyl)-2,8,12,17-tetramethyl-porphyrin-5-yl ester

There total 13 articles about Benzoic acid (5E,10Z,14Z,19Z)-13,18-bis-(2-hydroxy-ethyl)-3,7-bis-(2-methoxycarbonyl-ethyl)-2,8,12,17-tetramethyl-porphyrin-5-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 79760-29-5
2,4-bis(2-acetoxyethyl)-γ-benzoyloxy-6,7-bis(2-methoxycarbonylethyl)-1,3,5,8-tetramethylporphyrin

: 79760-30-8
Benzoic acid (5E,10Z,14Z,19Z)-13,18-bis-(2-hydroxy-ethyl)-3,7-bis-(2-methoxycarbonyl-ethyl)-2,8,12,17-tetramethyl-porphyrin-5-yl ester

Guidance literature:: With sulfuric acid; In methanol; for 1h; Heating;
DOI:10.1016/S0040-4020(01)88698-1

Reference yield:

: 4792-10-3
3-{5-Formyl-2-[5-formyl-3-(2-methoxycarbonyl-ethyl)-4-methyl-1H-pyrrol-2-ylmethyl]-4-methyl-1H-pyrrol-3-yl}-propionic acid methyl ester

: 79760-30-8
Benzoic acid (5E,10Z,14Z,19Z)-13,18-bis-(2-hydroxy-ethyl)-3,7-bis-(2-methoxycarbonyl-ethyl)-2,8,12,17-tetramethyl-porphyrin-5-yl ester

Guidance literature:: Multi-step reaction with 4 steps

1: SO₂Cl₂

2: 48 percent / TFA / 2 h / 20 °C

3: pyridine

4: acid / methanol

With sulfuryl dichloride; trifluoroacetic acid; In pyridine; methanol;
DOI:10.1039/c39810000763

Reference yield:

: 75630-46-5
benzyl 5-acetoxymethyl-3-(methoxycarbonylmethyl)-4-methylpyrrole-2-carboxylate

: 79760-30-8
Benzoic acid (5E,10Z,14Z,19Z)-13,18-bis-(2-hydroxy-ethyl)-3,7-bis-(2-methoxycarbonyl-ethyl)-2,8,12,17-tetramethyl-porphyrin-5-yl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 81 percent / SnCl₄ / CH₂Cl₂ / 1.5 h / -10 - 0 °C

2: 90 percent / diborane / tetrahydrofuran / 4.5 h

3: 90 percent / pyridine / 2 h / Ambient temperature

4: H₂, Et₃N / 10percent Pd-C / methanol / 20 °C / 760 Torr

5: trifluoroacetic acid / 2 h

6: pyridine / 0.5 h

7: 96 percent / 5percent H₂SO₄ / methanol / 1 h / Heating

With sulfuric acid; hydrogen; tin(IV) chloride; triethylamine; trifluoroacetic acid; diborane; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; dichloromethane;
DOI:10.1016/S0040-4020(01)88698-1