trifluoromethanesulfonic acid 2-(2-ethoxycarbonylamino-ethyl)phenyl ester

Base Information

Chemical Name:trifluoromethanesulfonic acid 2-(2-ethoxycarbonylamino-ethyl)phenyl ester
CAS No.:608519-06-8
Molecular Formula:C₁₂H₁₄F₃NO₅S
Molecular Weight:341.308
Hs Code.:

Synonyms:trifluoromethanesulfonic acid 2-(2-ethoxycarbonylamino-ethyl)phenyl ester

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Chemical Property of trifluoromethanesulfonic acid 2-(2-ethoxycarbonylamino-ethyl)phenyl ester

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Technology Process of trifluoromethanesulfonic acid 2-(2-ethoxycarbonylamino-ethyl)phenyl ester

There total 6 articles about trifluoromethanesulfonic acid 2-(2-ethoxycarbonylamino-ethyl)phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 37595-74-7
N,N-phenylbistrifluoromethane-sulfonimide

: 608519-05-7
[2-(2-hydroxyphenyl)ethyl]carbamic acid ethyl ester

: 608519-06-8
trifluoromethanesulfonic acid 2-(2-ethoxycarbonylamino-ethyl)phenyl ester

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃; for 48h;
DOI:10.1016/S0040-4020(03)01073-1

Reference yield:

: 48179-00-6
3-(2'-(Benzyloxy)phenyl)propionic Acid

: 608519-06-8
trifluoromethanesulfonic acid 2-(2-ethoxycarbonylamino-ethyl)phenyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: diphenylphosphoryl azide; Et₃N / toluene / 1 h / Heating

1.2: 94 percent / CuCl₂ / toluene / 1 h / Heating

2.1: 100 percent / H₂ / Pd/C / ethyl acetate / 2 h / 20 °C / 760 Torr

3.1: 89 percent / Et₃N / CH₂Cl₂ / 48 h / 20 °C

With diphenylphosphoranyl azide; hydrogen; triethylamine; palladium on activated charcoal; In dichloromethane; ethyl acetate; toluene; 1.2: Curtius rearrangement;
DOI:10.1016/S0040-4020(03)01073-1

Reference yield:

: 119-84-6,1341-36-2
C₆H₄(CH₂CH₂C(O)O)

: 608519-06-8
trifluoromethanesulfonic acid 2-(2-ethoxycarbonylamino-ethyl)phenyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: 96 percent / tetrahydrofuran; H₂O / 0.5 h / 20 °C

2.1: 100 percent / tetrabutylammonium bromide; NaH / tetrahydrofuran / 1 h / 20 °C

3.1: 93 percent / aq. KOH / ethanol / 22 h / Heating

4.1: diphenylphosphoryl azide; Et₃N / toluene / 1 h / Heating

4.2: 94 percent / CuCl₂ / toluene / 1 h / Heating

5.1: 100 percent / H₂ / Pd/C / ethyl acetate / 2 h / 20 °C / 760 Torr

6.1: 89 percent / Et₃N / CH₂Cl₂ / 48 h / 20 °C

With potassium hydroxide; diphenylphosphoranyl azide; tetrabutylammomium bromide; hydrogen; sodium hydride; triethylamine; palladium on activated charcoal; In tetrahydrofuran; ethanol; dichloromethane; water; ethyl acetate; toluene; 4.2: Curtius rearrangement;
DOI:10.1016/S0040-4020(03)01073-1