(+)-(2S,3S)-1-(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-2,3-dimethoxybutane

Base Information

Chemical Name:(+)-(2S,3S)-1-(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-2,3-dimethoxybutane
CAS No.:107291-11-2
Molecular Formula:C₁₉H₃₄O₄Si
Molecular Weight:354.562
Hs Code.:

Synonyms:(+)-(2S,3S)-1-(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-2,3-dimethoxybutane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+)-(2S,3S)-1-(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-2,3-dimethoxybutane

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Technology Process of (+)-(2S,3S)-1-(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-2,3-dimethoxybutane

There total 3 articles about (+)-(2S,3S)-1-(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-2,3-dimethoxybutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 107291-10-1
(+)-(2S,3S)-4-(benzyloxy)-2,3-dimethoxy-1-butanol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 107291-11-2
(+)-(2S,3S)-1-(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-2,3-dimethoxybutane

Guidance literature:: With 1H-imidazole; dmap; In dichloromethane; for 3h;
DOI:10.1021/jo00235a011

Reference yield:

: 24679-72-9
(2S,3S)-2,3-dimethoxy-1,4-butanediol

: 107291-11-2
(+)-(2S,3S)-1-(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-2,3-dimethoxybutane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaH / 1.) DMF, -30 deg C, 1 h, 2.) 1 h

2: 100 percent / imidazole, 4-(dimethylamino)pyridine / CH₂Cl₂ / 3 h

With 1H-imidazole; dmap; sodium hydride; In dichloromethane;
DOI:10.1021/jo00235a011

Reference yield:

: 27957-93-3
(+)-(2R,3R)-diethyl di-O-methyltartrate

: 107291-11-2
(+)-(2S,3S)-1-(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-2,3-dimethoxybutane

Guidance literature:: Multi-step reaction with 3 steps

1: LiAlH₄ / tetrahydrofuran / 1 h / 0 °C

2: 1.) NaH / 1.) DMF, -30 deg C, 1 h, 2.) 1 h

3: 100 percent / imidazole, 4-(dimethylamino)pyridine / CH₂Cl₂ / 3 h

With 1H-imidazole; dmap; lithium aluminium tetrahydride; sodium hydride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00235a011