(3S,5S)-3,5-Bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]cyclohexanone

Base Information

Chemical Name:(3S,5S)-3,5-Bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]cyclohexanone
CAS No.:139356-35-7
Molecular Formula:C₁₈H₃₈O₃Si₂
Molecular Weight:358.669
Hs Code.:
DSSTox Substance ID:DTXSID601161665

Synonyms:SCHEMBL3179253;DTXSID601161665;(3S,5S)-3,5-Bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]cyclohexanone

Suppliers and Price of (3S,5S)-3,5-Bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]cyclohexanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of (3S,5S)-3,5-Bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]cyclohexanone

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:358.23594814
Heavy Atom Count:23
Complexity:393

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OC1CC(CC(=O)C1)O[Si](C)(C)C(C)(C)C
Isomeric SMILES:CC(C)(C)[Si](C)(C)O[C@H]1C[C@@H](CC(=O)C1)O[Si](C)(C)C(C)(C)C

Technology Process of (3S,5S)-3,5-Bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]cyclohexanone

There total 36 articles about (3S,5S)-3,5-Bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]cyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: (3R,5S)-3,5-dihydroxycyclohexanone

: 139356-35-7
(3R,5S)-3,5-bis[(tert-butyldimethylsilyl)oxy]cyclohexanone

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 0.5h;
DOI:10.1016/j.tetlet.2013.06.061

Reference yield: 70.0%

: 389084-26-8
3,5-di(tert-butyldimethylsilyloxy)cyclohexan-1-ol

: 139356-35-7
3,5-di-(tert-butyl-dimethylsilyloxy)-(3S,5S)-cyclohexan-1-one

Guidance literature:: With sodium acetate; pyridinium chlorochromate; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1021/jo016141g

Reference yield:

: C₁₈H₄₀O₃Si₂

: 139356-35-7
(3R,5S)-3,5-bis[(tert-butyldimethylsilyl)oxy]cyclohexanone

Guidance literature:: With sodium acetate; pyridinium chlorochromate; In dichloromethane; at 0 ℃; for 0.25h; Inert atmosphere;
DOI:10.1248/cpb.c16-00311