Technology Process of dimethyl (2S,3R,4S,5S)-2-acetoxy-3,4,5-tris(benzyloxy)cyclohexane-1,1-dicarboxylate
There total 18 articles about dimethyl (2S,3R,4S,5S)-2-acetoxy-3,4,5-tris(benzyloxy)cyclohexane-1,1-dicarboxylate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1: mercury(II)chloride / acetonitrile; H2O
2: 85 percent / acetic anhydride / pyridine / 48 h / Ambient temperature
3: H2 / Raney nickel
4: tetrabutylammonium fluoride
5: 1.) PCC / 1.) CH2Cl2, 2.) pyridine
With
tetrabutyl ammonium fluoride; hydrogen; acetic anhydride; pyridinium chlorochromate; mercury dichloride;
nickel;
In
pyridine; water; acetonitrile;
DOI:10.1246/cl.1986.1081
- Guidance literature:
-
Multi-step reaction with 6 steps
1: imidazole / dimethylformamide
2: mercury(II)chloride / acetonitrile; H2O
3: 85 percent / acetic anhydride / pyridine / 48 h / Ambient temperature
4: H2 / Raney nickel
5: tetrabutylammonium fluoride
6: 1.) PCC / 1.) CH2Cl2, 2.) pyridine
With
1H-imidazole; tetrabutyl ammonium fluoride; hydrogen; acetic anhydride; pyridinium chlorochromate; mercury dichloride;
nickel;
In
pyridine; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1246/cl.1986.1081
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 85 percent / acetic anhydride / pyridine / 48 h / Ambient temperature
2: H2 / Raney nickel
3: tetrabutylammonium fluoride
4: 1.) PCC / 1.) CH2Cl2, 2.) pyridine
With
tetrabutyl ammonium fluoride; hydrogen; acetic anhydride; pyridinium chlorochromate;
nickel;
In
pyridine;
DOI:10.1246/cl.1986.1081
