TRICHLOROTRIS(TETRAHYDROFURAN)VANADIUM

Base Information

• Chemical Name: TRICHLOROTRIS(TETRAHYDROFURAN)VANADIUM
• CAS No.: 19559-06-9
• Molecular Formula: C12H24 Cl3 O3 V
• Molecular Weight: 373.621
• Hs Code.: 29321900
• Mol file: 19559-06-9.mol

Synonyms:Furan,tetrahydro-, vanadium complex; Trichlorotris(tetrahydrofuran)vanadium;Tris(tetrahydrofuran)vanadium trichloride; Vanadium trichloridetris(tetrahydrofuran); vanadium trichloride complex with THF (1:3)

Chemical Property of TRICHLOROTRIS(TETRAHYDROFURAN)VANADIUM

Chemical Property:

• Vapor Pressure: 152mmHg at 25°C
• Melting Point: 265 °C (dec.)(lit.)
• Boiling Point: 40 °C
• Flash Point: 18 °F
• PSA: 9.23000
• Density: 1.312 g/mL at 25 °C
• LogP: 2.86530
• Storage Temp.: 2-8°C
• Sensitive.: moisture sensitive, store cold

Purity/Quality:

98%,99%, ^*data from raw suppliers

Vanadium(III) chloride tetrahydrofuran adduct ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C,F
• Statements: 20/21/22-34-40-11
• Safety Statements: 26-27-28-36/37/39-45-23-16

MSDS Files:

Useful:

Technology Process of TRICHLOROTRIS(TETRAHYDROFURAN)VANADIUM

There total 10 articles about TRICHLOROTRIS(TETRAHYDROFURAN)VANADIUM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + vanadium(III) chloride → Vanadium (III) chloride-(tris-tetrahydrofuran) (131063-11-1,16997-51-6,19559-06-9)

Guidance literature:

at 75 ℃; for 48h; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201904103

Reference yield: 99.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + vanadium(III) chloride (7718-98-1) → Vanadium (III) chloride-(tris-tetrahydrofuran) (131063-11-1,16997-51-6,19559-06-9)

Guidance literature:

In tetrahydrofuran; heating overnight; hot filtration, crystn. at room temp.;

Reference yield: 90.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + vanadiumtetrachloride (7632-51-1) → VCl3(tetrahydrofuran)3 (131063-11-1,1372665-07-0,16997-51-6,19559-06-9)

Guidance literature:

With triethylboron; In dichloromethane; under Ar or N2; THF was cooled in an ice bath, VCl4 in CH2Cl2 was added, BEt3 was added, warmed to 90°C (oil bath) for 1 h; cooling, filtn., washing, drying in a glovebox;

upstream raw materials:

vanadium(III) chloride

tetrahydrofuran

bismesitylenevanadium(I) iodide

vanadiumtetrachloride

Downstream raw materials:

chloro(5,10,15,20-meso-tetra-p-tolylporphyrinato)vanadium(III)

(hexacarbonyl)vanadinate^(1-)

tris-(triphenylsiloxy)-vanadium oxide

(2,6-Me₂-C₆H₃O)Cl₂(tetrahydrofuran)2 vanadium(III)