Vanadium(III) chloride

Base Information

• Chemical Name: Vanadium(III) chloride
• CAS No.: 7718-98-1
• Molecular Formula: VCl3
• Molecular Weight: 157.3
• Hs Code.: 28273990
• European Community (EC) Number: 231-744-6
• UN Number: 2475
• DSSTox Substance ID: DTXSID3064776
• Wikipedia: Vanadium(III) chloride
• Wikidata: Q421260
• Mol file: 7718-98-1.mol

Synonyms:Vanadium(III) chloride;7718-98-1;Vanadium chloride (VCl3);Vanadium trichloride;trichlorovanadium;CCRIS 8889;EINECS 231-744-6;UN2475;MFCD00011454;Cl3V;VCl3;Cl3-V;vanadium(3+) trichloride;Vanadium( cento) chloride;Cloruro de vanadio (vcl3);VANADIUM (III) CHLORIDE;Vanadium(III) chloride, 97%;DTXSID3064776;Vanadium(III) chloride, anhydrous;NA2475;LS-161384;Vanadium trichloride [UN2475] [Corrosive];Vanadium trichloride [UN2475] [Corrosive];Q421260

Chemical Property of Vanadium(III) chloride

Chemical Property:

• Appearance/Colour: dark blue to violet to black powder
• Melting Point: 250 °C
• PSA: 0.00000
• Density: 3 g/mL at 25 °C(lit.)
• LogP: 2.06850
• Storage Temp.: water-free area
• Sensitive.: Moisture Sensitive
• Solubility.: Soluble in tetrahydrofuran, alcohol, ether and hydrocarbons.
• Water Solubility.: decomposes in H2O; soluble alcohol, ether [HAW93]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 155.850516
• Heavy Atom Count: 4
• Complexity: 8
• Transport DOT Label: Corrosive

Purity/Quality:

99.9% ^*data from raw suppliers

VanadiumChloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 22-34
• Safety Statements: 26-27-28-36/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: Cl[V](Cl)Cl
• Recent EU Clinical Trials: Clinical Evaluation of Metal Panel Allergens: Aluminum, Copper, Manganese, Molybdenum, Tin, Titanium, Vanadium and Zinc Dose Response Study
• Uses: Vanadium(III) chloride has been used as a catalyst for Biginelli condensation. As a reducing agent, it is capable of converting nitrate to nitrite in water samples, allowing for the direct detection of nitrates. Preparation of vanadium dichloride and organovanadium compounds.

Technology Process of Vanadium(III) chloride

There total 78 articles about Vanadium(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

vanadiumtetrachloride (7632-51-1) → vanadium(III) chloride (7718-98-1)

Guidance literature:

With hydrogen sulfide; In benzene; treatment with H2S about 20 min at ambiente temp.;; washing pptn. with CCl4 and drying in vacuum at 2 torr and 150°C;;

Reference yield: 96.0%

vanadium hexacarbonyl (14024-00-1) → vanadium(III) chloride (7718-98-1)

Guidance literature:

With hydrogen chloride; In n-heptane; byproducts: carbon monoxide, dihydrogen; under Ar or N2, exclusion of light, at -78°C, warmed to -40°C; pptn. filtered off at room temp.;

DOI:10.1016/S0277-5387(00)80722-6

Reference yield: 90.0%

thionyl chloride (7719-09-7) + vanadium(V) oxychloride (7727-18-6) → vanadium(III) chloride (7718-98-1)

Guidance literature:

With N₂H₅Cl; In tetrachloromethane; heating 10 - 15 h under N2 at reflux;; heating with CS2; pptn. washing with CHCl3 and ether;;

upstream raw materials:

hydrogenchloride

bis(mesitylene)vanadium⁽⁰⁾

vanadium

Iodine monochloride

Downstream raw materials:

vanadium(III) fluoride

vanadium trichloride tristetrahydrofuran

vanadium pentafluoride

orthovanadate

Refernces

• 1、 Tougait, Olivier,Ibers, James A.. "Synthesis and characterization of the rare-earth vanadium oxyselenides Ln7VO4SE8 (Ln = Nd, Sm, Gd)". . p. 564 - 568. Retrieved 2000.
• 2、 Drake, J. E.,Vekris, J.,Wood, J. S.. "". . p. 3380 - 3382. Retrieved 1968.
• 3、 Troyanov. "Crystal structures of SbCl5, VCl4, and VOCl 3". . p. 1727 - 1732. Retrieved 2008/10/09.