(E)-2,2,3,3,12,12,13,13-octamethyl-4,11-dioxa-3,12-disilatetradec-7-ene

Base Information

Chemical Name:(E)-2,2,3,3,12,12,13,13-octamethyl-4,11-dioxa-3,12-disilatetradec-7-ene
CAS No.:240431-99-6
Molecular Formula:C₁₈H₄₀O₂Si₂
Molecular Weight:344.685
Hs Code.:

Synonyms:(E)-2,2,3,3,12,12,13,13-octamethyl-4,11-dioxa-3,12-disilatetradec-7-ene

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Chemical Property of (E)-2,2,3,3,12,12,13,13-octamethyl-4,11-dioxa-3,12-disilatetradec-7-ene

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Technology Process of (E)-2,2,3,3,12,12,13,13-octamethyl-4,11-dioxa-3,12-disilatetradec-7-ene

There total 1 articles about (E)-2,2,3,3,12,12,13,13-octamethyl-4,11-dioxa-3,12-disilatetradec-7-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 627-27-0
homoalylic alcohol

: 135579-12-3
N-(but-3-enyl)-N-phenylacetamide

: 18162-48-6
tert-butyldimethylsilyl chloride

: N-(6-(tert-butyldimethylsilyloxy)hex-3-enyl)-N-phenylethanamide

: 165276-60-8
(Z)-1,6-di(tert-butyldimethylsilyloxy)hex-3-ene

: N,N'-(hex-3-ene-1,6-diyl)bis(N-phenylethanamide)

: 240431-99-6
(E)-2,2,3,3,12,12,13,13-octamethyl-4,11-dioxa-3,12-disilatetradec-7-ene

Guidance literature:: homoalylic alcohol; N-(but-3-enyl)-N-phenylacetamide; With 2,6-dichloro-1,4-benzoquinone; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; for 168h; Heating;

tert-butyldimethylsilyl chloride; With 1H-imidazole; In dichloromethane; at 20 ℃; for 18h; Further stages.;
DOI:10.1016/j.tet.2008.06.067

Reference yield: 49.0%

: 240431-99-6
(E)-2,2,3,3,12,12,13,13-octamethyl-4,11-dioxa-3,12-disilatetradec-7-ene

: 94108-33-5
dec-9-en-1-yl benzoate

: benzoic acid 12-(tert-butyl-dimethyl-silanyloxy)-dodec-9-enyl ester

: C₃₂H₄₄O₄

: C₃₂H₄₄O₄

Guidance literature:: With Grubbs catalyst first generation; In dichloromethane; for 3h; Heating;
DOI:10.1021/ja993063u

Reference yield:

: 240431-99-6
(E)-2,2,3,3,12,12,13,13-octamethyl-4,11-dioxa-3,12-disilatetradec-7-ene

: C₃₂H₅₀O₆Si₂

Guidance literature:: Multi-step reaction with 3 steps

1.1: (S)-1-(2-(diphenylphosphanyl)naphthalen-1-yl)isoquinoline; (bicyclo[2.2.1]hepta-2,5-diene)-(2,4-pentanedionato)-rhodium / tetrahydrofuran / 0.08 h / Inert atmosphere; Glovebox

1.2: 40 h / 20 °C / Inert atmosphere; Sealed tube

1.3: 1 h / 20 °C

2.1: dihydrogen peroxide; sodium hydroxide / tetrahydrofuran / 0 - 20 °C

3.1: dmap; triethylamine / dichloromethane / 0 - 20 °C

With dmap; (bicyclo[2.2.1]hepta-2,5-diene)-(2,4-pentanedionato)-rhodium; dihydrogen peroxide; triethylamine; (S)-1-(2-(diphenylphosphanyl)naphthalen-1-yl)isoquinoline; sodium hydroxide; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jacs.1c07778