meso-Tetratolylporphyrin-Cu(II)

Base Information

• Chemical Name: meso-Tetratolylporphyrin-Cu(II)
• CAS No.: 19414-66-5
• Molecular Formula: C48H36 Cu N4
• Molecular Weight: 732.387
• Mol file: 19414-66-5.mol

Synonyms:Copper,[5,10,15,20-tetra-p-tolylporphinato(2-)]- (8CI); Copper,[5,10,15,20-tetrakis(4-methylphenyl)-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-4-1)-; 21H,23H-Porphine, 5,10,15,20-tetrakis(4-methylphenyl)-, coppercomplex; (meso-Tetra-p-tolylporphinato)copper;(meso-Tetrakis(p-tolyl)porphyrinato)copper(II)

Chemical Property of meso-Tetratolylporphyrin-Cu(II)

Chemical Property:

• PSA: 15.88000
• LogP: 7.66890

Purity/Quality:

98.5% ^*data from raw suppliers

5,10,15,20-Tetra(4-methylphenyl)-21H,23H-porphinecopper 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of meso-Tetratolylporphyrin-Cu(II)

There total 8 articles about meso-Tetratolylporphyrin-Cu(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

copper(II) acetate monohydrate (6046-93-1) + 5,10,15,20-tetra(p-tolyl)porphyrin (14527-51-6) → 5,10,15,20-tetrakis(4-methylphenyl)porphyrinatocopper(II) (19414-66-5)

Guidance literature:

With acetic acid; In dichloromethane; at 20 ℃; for 0.25h;

DOI:10.1016/j.bmc.2016.09.060

Reference yield: 96.0%

copper(II) acetate dihydrate + 5,10,15,20-tetra(p-tolyl)porphyrin (14527-51-6) → 5,10,15,20-tetrakis(4-methylphenyl)porphyrinatocopper(II) (19414-66-5)

Guidance literature:

In methanol; chloroform; at 20 ℃;

DOI:10.1016/j.molstruc.2019.04.013

Reference yield:

5,10,15,20-tetra(p-tolyl)porphyrin (14527-51-6) → copper(II) 5,10,15,20-tetratolylporphyrin (19414-66-5)

Guidance literature:

With copper(II) acetate monohydrate; acetic acid; In methanol; chloroform; at 50 - 60 ℃; for 3h;

DOI:10.1142/S1088424613500612

upstream raw materials:

5,10,15,20-tetra(p-tolyl)porphyrin

copper diacetate

copper(II) bis(trifluoromethanesulfonate)

pyrrole

Downstream raw materials:

C₄₉H₃₈N₄O

β-formyl-5,10,15,20-tetrakis(4-methylphenyl)porphyrin copper(II)

Refernces

• 1、 Wu, Zhen-Yi,Yang, Sheng-Yan. "Synthesis, spectral and redox properties of closely spaced pyrrole-β-position-linked porphyrin-fullerene dyads". . p. 244 - 254. Retrieved 2019/04/17.
• 2、 Liao, Ping-Yong,Gao, Ying-Hua,Wang, Xin-Rong,Bao, Lei-Lei,Bian, Jun,Hu, Tai-Shan,Zheng, Mei-Zhen,Yan, Yi-Jia,Chen, Zhi-Long. "Tetraphenylporphyrin derivatives possessing piperidine group as potential agents for photodynamic therapy". . p. 213 - 219. Retrieved 2016/11/18.