Cupric acetate monohydrate

Base Information

• Chemical Name: Cupric acetate monohydrate
• CAS No.: 6046-93-1
• Molecular Formula: Cu(C2H4O2)2^.H2O
• Molecular Weight: 199.651
• Hs Code.: 29152900
• Mol file: 6046-93-1.mol

Synonyms:Copper(2+) acetate monohydrate;Copper(II) acetatemonohydrate;copper(2+) acetate hydrate (1:2:1);acetic acid, copper(2+) salt, hydrate (2:1:1);

Chemical Property of Cupric acetate monohydrate

Chemical Property:

• Appearance/Colour: Dark green small crystal with odour of acetic acid
• Melting Point: 115 °C
• Boiling Point: 117.1 °C at 760 mmHg
• Flash Point: 40 °C
• PSA: 89.49000
• Density: 1.882
• LogP: -2.55440
• Storage Temp.: Store at +5°C to +30°C.
• Solubility.: 72g/l
• Water Solubility.: 72 g/L (20 ºC)

Purity/Quality:

99.9% ^*data from raw suppliers

Copper(II) Acetate Monohydrate >95.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn; N; Xi
• Hazard Codes: Xn,N,Xi,C
• Statements: 22-36/37/38-50/53-34
• Safety Statements: 36/37/39-60-61-36-26-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Copper(II) acetate is used as a pigment for ceramics; in the manufacture of Paris green; in textile dyeing; as a fungicide; and as a catalyst.Copper(II) acetate monohydrate is used in DNA extraction in biochemical applications. It is also used as a catalyst or oxidizing agent in organic syntheses.Catalyst for activation of alcohols as greener alkylating reagents.Copper-Catalyzed Aerobic Oxidation of Amines to Imines under Neat Conditions with Low Catalyst Loading. Cupric acetate monohydrate can be used in preparation of Fehling's reagent for sugars Copper(II) acetate monohydrate is used in formation of Cu chelates of ?-dicarbonyl compounds as a means of purification and in the eglinton (modified glaser) coupling of terminal alkynes. It is also used as a catalyst for the michael reaction giving increased yields and absence of side-reactions. It Promotes ullmann-type C-O and C-N coupling reactions of arylboronic acids with phenols, amines and various other nitrogen derivatives. It is also used in biochemical applications such as DNA extraction. Catalyst for activation of alcohols as greener alkylating reagentsCopper-Catalyzed Aerobic Oxidation of Amines to Imines under Neat Conditions with Low Catalyst Loading

Technology Process of Cupric acetate monohydrate

There total 37 articles about Cupric acetate monohydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Cu(tris(3,5-dimethylpyrazolyl)methane)(NO2)] + acetic acid (64-19-7,77671-22-8) → copper(II) acetate monohydrate (6046-93-1)

Guidance literature:

In dichloromethane; solvent-removed, crystd. (CH2Cl2/Et2O); Kinetics;

DOI:10.1021/ja075575b

Reference yield:

(tris(3,5-diethyl-1-pyrazolyl)methane)Cu(NO2) + acetic acid (64-19-7,77671-22-8) → copper(II) acetate monohydrate (6046-93-1)

Guidance literature:

In dichloromethane; solvent-removed, crystd. (CH2Cl2/Et2O); Kinetics;

DOI:10.1021/ja075575b

Reference yield:

(tris(3,5-diisopropyl-1-pyrazolyl)methane)Cu(NO2) + acetic acid (64-19-7,77671-22-8) → copper(II) acetate monohydrate (6046-93-1)

Guidance literature:

In dichloromethane; solvent-removed, crystd. (CH2Cl2/Et2O); Kinetics;

DOI:10.1021/ja075575b

upstream raw materials:

sodium acetate

calcium acetate

acetic acid

water

Downstream raw materials:

Benzyl 6α-(formamido)-6β-(phenoxyacetamido)penicillanate

bis{2-[(2-hydroxyethyl)iminomethyl]phenolato}copper(II)

bis((N-(4-(4'-n-(C₁₂H₂₅)Obenzoyloxy)salicidene)-4-n-butylphenyl)iminato) copper(II)

Refernces

• 1、 Sidhu, S. S.,Berger, J. A.. "". . p. 322 - 323. Retrieved 1939.
• 2、 Zeleoak,Vargova,Gyoeryova, Katalin,Vecernikova,Balek. "Copper(II) acetates with aliphatic/heterocyclic amines: Coupled TG-DTA-EGA study, IR characterization and structure correlation". . p. 747 - 754. Retrieved 2005.
• 3、 Muthusami, Rubiga,Moorthy, Malathy,Irena, Kostova,Govindaraj, Anbarasu,Manickam, Chozhanathmisra,Rangappan, Rajavel. "Designing a biomimetic catalyst for phenoxazinone synthase activity using a mesoporous Schiff base copper complex with a novel double-helix morphology". . p. 18608 - 18620. Retrieved 2018/11/27.