alpha-Furfuryliden-alpha-furylmethylamine

Base Information

• Chemical Name: alpha-Furfuryliden-alpha-furylmethylamine
• CAS No.: 19377-82-3
• Molecular Formula: C10H9 N O2
• Molecular Weight: 175.187
• Hs Code.: 2932190090
• Mol file: 19377-82-3.mol

Synonyms:Furfurylamine,N-furfurylidene- (8CI); 2-N-(Furylidene)furfurylamine;N-Furfurylidenefurfurylamine

Chemical Property of alpha-Furfuryliden-alpha-furylmethylamine

Chemical Property:

• Boiling Point: 259.0±25.0 °C(Predicted)
• PKA: 4.37±0.50(Predicted)
• PSA: 38.64000
• Density: 1.13±0.1 g/cm3(Predicted)
• LogP: 2.49170

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of alpha-Furfuryliden-alpha-furylmethylamine

There total 14 articles about alpha-Furfuryliden-alpha-furylmethylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

furfural (98-01-1) → N-furfurylidenefurfurylamine (19377-82-3) + furan-2-ylmethanamine (617-89-0) + 2,4,5-tris(2-furyl)imidazoline (550-23-2)

Guidance literature:

With ammonia; hydrogen; In methanol; at 100 ℃; for 0.25h; under 22502.3 Torr; Reagent/catalyst; Autoclave; Green chemistry;

DOI:10.1016/j.mcat.2019.110755

Reference yield: 65.0%

furan-2-ylmethanamine (617-89-0) → N-furfurylidenefurfurylamine (19377-82-3) + bis((furan-2-yl)methyl)amine (18240-50-1)

Guidance literature:

palladium; at 140 ℃; for 10h;

DOI:10.1021/ja00353a025

Reference yield: 40.0%

furfural (98-01-1) → TETRAHYDROFURFURYLAMINE (4795-29-3) + N-furfurylidenefurfurylamine (19377-82-3) + furan-2-ylmethanamine (617-89-0)

Guidance literature:

With 0.5% Ru/activated carbon; ammonia; hydrogen; In methanol; at 100 ℃; for 0.25h; under 22502.3 Torr; Autoclave; Green chemistry;

DOI:10.1016/j.mcat.2019.110755

upstream raw materials:

furan-2-ylmethanamine

(2-furyl)methyl alcohol

furfural

2-furancarbonitrile

Downstream raw materials:

furan-2-ylmethanamine

TETRAHYDROFURFURYLAMINE

bis((furan-2-yl)methyl)amine

fuberidazole

Refernces

• 1、 Fan, Xiaomeng,Gao, Jin,Gao, Mingxia,Jia, Xiuquan,Ma, Jiping,Xu, Jie. "Self-regulated catalysis for the selective synthesis of primary amines from carbonyl compounds". supporting information. p. 7115 - 7121. Retrieved 2021/09/28.
• 2、 Dong, Chenglong,Wang, Hongtao,Du, Haochen,Peng, Jiebang,Cai, Yang,Guo, Shuai,Zhang, Jianli,Samart, Chanatip,Ding, Mingyue. "Ru/HZSM-5 as an efficient and recyclable catalyst for reductive amination of furfural to furfurylamine". . . Retrieved 2020/01/02.