5,15-bis(4-[1,3,2]-dioxaborinan-2-yl-phenyl)porphyrinatozinc(II)

Base Information

• Chemical Name: 5,15-bis(4-[1,3,2]-dioxaborinan-2-yl-phenyl)porphyrinatozinc(II)
• CAS No.: 291278-84-7
• Molecular Formula: C₃₈H₃₀B₂N₄O₄Zn
• Molecular Weight: 693.693
• Mol file: 291278-84-7.mol

Synonyms:5,15-bis(4-[1,3,2]-dioxaborinan-2-yl-phenyl)porphyrinatozinc(II)

Chemical Property of 5,15-bis(4-[1,3,2]-dioxaborinan-2-yl-phenyl)porphyrinatozinc(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,15-bis(4-[1,3,2]-dioxaborinan-2-yl-phenyl)porphyrinatozinc(II)

There total 2 articles about 5,15-bis(4-[1,3,2]-dioxaborinan-2-yl-phenyl)porphyrinatozinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

5,15-bis(4-dihydroxyboronophenyl)porphyrinatozinc(II) dihydrate + trimethyleneglycol (504-63-2) → 5,15-bis(4-[1,3,2]-dioxaborinan-2-yl-phenyl)porphyrinatozinc(II) (291278-84-7)

Guidance literature:

In benzene; the mixt. was refluxed overnight; the residue was washed with water, the org. layer was dried over anhyd. Na2SO4, the solvent was evapd.;

DOI:10.1021/ja010806e

Reference yield: 98.0%

di(pyrrol-2-yl)methane (21211-65-4) + zinc diacetate (557-34-6) + 4-(1,3,2-dioxaborinan-2-yl)-benzaldehyde → 5,15-bis(4-[1,3,2]-dioxaborinan-2-yl-phenyl)porphyrinatozinc(II) (291278-84-7)

Guidance literature:

With trimethyleneglycol; In methanol; dichloromethane; chloroform; dipyrrylmethane and dioxaborinan-2-yl mixed at room temp. in CH2Cl2, refluxed, zinc salt added (CHCl3-MeOH), refluxed, septd., propane-1,3-dioladded, refluxed in benzene;

DOI:10.1039/b003365k

Reference yield: 4.0%

5,15-bis(4-[1,3,2]-dioxaborinan-2-yl-phenyl)porphyrinatozinc(II) (291278-84-7) → [5,15-bis(4-[1,3,2]-dioxaborinan-2-yl-phenyl)porphyrinatozinc(II)]2 (291278-83-6)

Guidance literature:

With silver(I) hexafluorophosphate; In chloroform; acetonitrile; at room temp.;

DOI:10.1039/b003365k

upstream raw materials:

trimethyleneglycol

di(pyrrol-2-yl)methane

zinc diacetate

Downstream raw materials:

[5,15-bis(4-[1,3,2]-dioxaborinan-2-yl-phenyl)porphyrinatozinc(II)]2