Carbamic acid (2aS,3R,7dR)-4-benzyloxy-2a-hydroxy-5,7-dimethoxy-6-methyl-1,2,2a,3,7c,7d-hexahydro-2,7b-diaza-benzo[f]cyclopropa[cd]inden-3-ylmethyl ester

Base Information

Chemical Name:Carbamic acid (2aS,3R,7dR)-4-benzyloxy-2a-hydroxy-5,7-dimethoxy-6-methyl-1,2,2a,3,7c,7d-hexahydro-2,7b-diaza-benzo[f]cyclopropa[cd]inden-3-ylmethyl ester
CAS No.:123266-83-1
Molecular Formula:C₂₃H₂₇N₃O₆
Molecular Weight:441.484
Hs Code.:

Carbamic acid (2aS,3R,7dR)-4-benzyloxy-2a-hydroxy-5,7-dimethoxy-6-methyl-1,2,2a,3,7c,7d-hexahydro-2,7b-diaza-benzo[f]cyclopropa[cd]inden-3-ylmethyl ester

Synonyms:Carbamic acid (2aS,3R,7dR)-4-benzyloxy-2a-hydroxy-5,7-dimethoxy-6-methyl-1,2,2a,3,7c,7d-hexahydro-2,7b-diaza-benzo[f]cyclopropa[cd]inden-3-ylmethyl ester

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Chemical Property of Carbamic acid (2aS,3R,7dR)-4-benzyloxy-2a-hydroxy-5,7-dimethoxy-6-methyl-1,2,2a,3,7c,7d-hexahydro-2,7b-diaza-benzo[f]cyclopropa[cd]inden-3-ylmethyl ester

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Technology Process of Carbamic acid (2aS,3R,7dR)-4-benzyloxy-2a-hydroxy-5,7-dimethoxy-6-methyl-1,2,2a,3,7c,7d-hexahydro-2,7b-diaza-benzo[f]cyclopropa[cd]inden-3-ylmethyl ester

There total 1 articles about Carbamic acid (2aS,3R,7dR)-4-benzyloxy-2a-hydroxy-5,7-dimethoxy-6-methyl-1,2,2a,3,7c,7d-hexahydro-2,7b-diaza-benzo[f]cyclopropa[cd]inden-3-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 123266-82-0
Acetic acid (1S,2aR,3S,7dS)-4-benzyloxy-2a-ethanesulfonyl-5,7-dimethoxy-6-methyl-3-(2,2,2-trichloro-acetylcarbamoyloxymethyl)-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester

: 123266-83-1
Carbamic acid (2aS,3R,7dR)-4-benzyloxy-2a-hydroxy-5,7-dimethoxy-6-methyl-1,2,2a,3,7c,7d-hexahydro-2,7b-diaza-benzo[f]cyclopropa[cd]inden-3-ylmethyl ester

Guidance literature:: With sodium tetrahydroborate; ammonia; Yield given. Multistep reaction; 1.) CH₃OH, 23 deg C;
DOI:10.1021/ja00203a055

Reference yield: 60.0%

: 67-56-1
methanol

: 123266-83-1
Carbamic acid (2aS,3R,7dR)-4-benzyloxy-2a-hydroxy-5,7-dimethoxy-6-methyl-1,2,2a,3,7c,7d-hexahydro-2,7b-diaza-benzo[f]cyclopropa[cd]inden-3-ylmethyl ester

: 123266-84-2
Carbamic acid (2aS,3R,7dR)-4-benzyloxy-2a,5,7-trimethoxy-6-methyl-1,2,2a,3,7c,7d-hexahydro-2,7b-diaza-benzo[f]cyclopropa[cd]inden-3-ylmethyl ester

Guidance literature:: With camphor-10-sulfonic acid; at 23 ℃;
DOI:10.1021/ja00203a055

Reference yield:

: 123266-83-1
Carbamic acid (2aS,3R,7dR)-4-benzyloxy-2a-hydroxy-5,7-dimethoxy-6-methyl-1,2,2a,3,7c,7d-hexahydro-2,7b-diaza-benzo[f]cyclopropa[cd]inden-3-ylmethyl ester

: 50-07-7,69515-74-8,102679-62-9,111768-87-7,148091-11-6
(+/-)-Mitomycin C

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / 1.) camphorsulfonic acid / 23 °C

2: 1.) H₂ (1 atm), 2.) DDQ / 1.) 10percent Pd/C / 1.) ethanol, 2.) acetone, water, -78 deg C

3: 85 percent / NH₃ / methanol / 23 °C

With camphor-10-sulfonic acid; ammonia; hydrogen; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium on activated charcoal; In methanol;
DOI:10.1021/ja00203a055