(R)-(+)-Dimethyl-2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate

Base Information

Chemical Name:(R)-(+)-Dimethyl-2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate
CAS No.:18531-91-4
Molecular Formula:C₂₄H₁₈O₆
Molecular Weight:402.403
Hs Code.:
European Community (EC) Number:624-161-7,624-571-6
Nikkaji Number:J553.654E,J82.765G,J3.228.348I
Mol file:18531-91-4.mol

Synonyms:18531-91-4;(R)-(+)-Dimethyl-2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate;69678-00-8;(S)-(-)-Dimethyl-2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate;methyl 3-hydroxy-4-(2-hydroxy-3-methoxycarbonylnaphthalen-1-yl)naphthalene-2-carboxylate;(R)-(+)-DIMETHYL-2 2'-DIHYDROXY-1 1'-BI&;Oprea1_599631;Oprea1_610286;SCHEMBL5083672;SCOGIYZPQMECLW-UHFFFAOYSA-N;AKOS015915697;(R)-(+)-Dimethyl-2,2-dihydroxy-1,1-bi;4,4'-Bi(3-hydroxy-2-naphthoic acid methyl) ester;J-011887;(S)-DiMethyl 2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate;(S)-Dimethyl 2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate;Dimethyl (R)-2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate;(+)-2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylic acid dimethyl ester;(aR)-2,2'-Dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylic acid dimethyl ester;(aS)-2,2'-Dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylic acid dimethyl ester;(R)-(+)-Dimethyl-2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate, 98%;(S)-(-)-Dimethyl-2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate, 98%;(S)-(-)-Dimethyl-2,2-dihydroxy-1,1-binaphthalene-3,3-dicarboxylate,purum,98%

Suppliers and Price of (R)-(+)-Dimethyl-2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

JR MediChem
[1,1''-Binaphthalene]-3,3''-dicarboxylicacid,2,2''-dihydroxy-,3,3''-dimethylester,(1R)- 96%
2g
$ 980.00

American Custom Chemicals Corporation
(R)-(+)-DIMETHYL-2,2'-DIHYDROXY-1,1'-BINAPHTHALENE-3,3'-DICARBOXYLATE 95.00%
5MG
$ 504.88

Total 5 raw suppliers

Chemical Property of (R)-(+)-Dimethyl-2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate

Chemical Property:

Melting Point:245-248 °C(lit.)
Boiling Point:539.8±50.0 °C(Predicted)
PKA:7.84±0.50(Predicted)
Flash Point:185.671oC
PSA：93.06000
Density:1.361±0.06 g/cm3(Predicted)
LogP:4.64440
XLogP3:6.1
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:5
Exact Mass:402.11033829
Heavy Atom Count:30
Complexity:581

Purity/Quality:

99% ^*data from raw suppliers

[1,1''-Binaphthalene]-3,3''-dicarboxylicacid,2,2''-dihydroxy-,3,3''-dimethylester,(1R)- 96% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC2=CC=CC=C2C(=C1O)C3=C(C(=CC4=CC=CC=C43)C(=O)OC)O

Technology Process of (R)-(+)-Dimethyl-2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate

There total 30 articles about (R)-(+)-Dimethyl-2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 883-99-8
3-hydroxy-2-naphthoic acid methyl ester

: 47644-69-9,69678-00-8,18531-91-4
dimethyl 2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate

Guidance literature:: With (+)-1,2,3,4,1',2',3',4'-octahydro-1,1'-bisisoquinoline; copper chloride (II); In acetonitrile; at 20 ℃; for 27h;
DOI:10.1002/ejoc.200500301

Reference yield: 87.0%

: 883-99-8
3-hydroxy-2-naphthoic acid methyl ester

: 135-19-3
β-naphthol

: 47644-69-9,69678-00-8,18531-91-4
dimethyl 2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate

: 128702-23-8,145415-62-9,145415-63-0
(aS)-methyl 2,2'-dihydroxy-1,1'-binaphthalene-3-carboxylate

: 602-09-5
1,1'-bi-2-naphthol

Guidance literature:: With tert-butylamine; copper dichloride; In methanol; at 50 ℃; for 0.75h;

Reference yield: 86.0%

: 883-99-8
3-hydroxy-2-naphthoic acid methyl ester

: 98793-02-3
3-benzyloxynaphthalen-2-ol

: methyl 3'-benzyloxy-2,2'-dihydroxy-1,1'-binaphthalene-3-carboxylate

: 47644-69-9,69678-00-8,18531-91-4
dimethyl 2,2'-dihydroxy-1,1'-binaphthalene-3,3'-dicarboxylate

: 223903-31-9,342630-36-8,183015-33-0
3,3'-bis(benzyloxy)-1,1'-binaphthalene-2,2'-diol

Guidance literature:: With oxygen; (S,S)-2,2'-isopropylidenebis(4-phenyl-2-oxazoline); copper(l) chloride; In tetrahydrofuran; at 20 ℃; for 3h;
DOI:10.1016/j.tetlet.2005.06.098