[W(CO)5(PH(CH(SiMe₃)2)(OPh))]

Base Information

Chemical Name:[W(CO)5(PH(CH(SiMe₃)2)(OPh))]
CAS No.:1352656-20-2
Molecular Formula:C₁₈H₂₅O₆PSi₂W
Molecular Weight:608.388
Hs Code.:

[W(CO)5(PH(CH(SiMe<sub>3</sub>)2)(OPh))]

Synonyms:[W(CO)5(PH(CH(SiMe₃)2)(OPh))]

Suppliers and Price of [W(CO)5(PH(CH(SiMe₃)2)(OPh))]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [W(CO)5(PH(CH(SiMe₃)2)(OPh))]

Chemical Property:

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Technology Process of [W(CO)5(PH(CH(SiMe₃)2)(OPh))]

There total 1 articles about [W(CO)5(PH(CH(SiMe₃)2)(OPh))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 284684-50-0
{[bis(trimethylsilyl)methyl(chloro)phosphane-κP]pentacarbonyltungsten(0)}

: 139-02-6
sodium phenoxide

: 1352656-20-2
[W(CO)5(PH(CH(SiMe₃)2)(OPh))]

Guidance literature:: In diethyl ether; byproducts: NaCl; phosphane complex (1 mmol) in Et2O added to soln. of NaOPh (1.2 mmol) inEt2O under Ar at low temp. (-40°C), stirred overnight; gently warmed to ambient temp., filtered, solvent removed in vac., product washed with n-pentane at -50°C, crystallized from n-pentane, detd. by 1H NMR, 13C NMR, 31P NMR, IR, MS, elem. anal., XRD;
DOI:10.1002/ejic.201200368

Reference yield: 90.0%

: 865-49-6
chloroform-d1

: 1352656-20-2
[W(CO)5(PH(CH(SiMe₃)2)(OPh))]

: 1416967-42-4
[W(CO)5(PCl(CH(SiMe₃)2)(OPh))]

Guidance literature:: With 12-crown-4, lithium diisopropylamide; In diethyl ether; under Ar, soln. of phosphane complex (0.1 mmol) and 12-crown-4 (0.1 mmol) in Et2O added dropwise to soln. of lithium diisopropylamide at -78°C, stirred for 0.5 h, solvent evapd. in vac., solid dissolved in CDCl3; volatiles evapd., residue washed with n-pentane at ca. -60°C, dried, crystd. from Et2O at ambient temp., detd. by 1H NMR, 13C NMR, 31P NMR, IR, MS, elem. anal., XRD;
DOI:10.1002/ejic.201200368

Reference yield: 50.6%

: 294-93-9,64491-37-8
(1,4,7,10-tetraoxacyclododecane)

: 1352656-20-2
[W(CO)5(PH(CH(SiMe₃)2)(OPh))]

: [Li(12-crown-4)][W(CO)5(P(CH(SiMe₃)2)(OPh))]

Guidance literature:: With lithium diisopropylamide; In diethyl ether; byproducts: i-Pr2NH; W complex (0.2 mmol) and 12-crown-4 (0.2 mmol) in diethyl ether added dropwise to soln. of lithium diisopropylamide (0.22 mmol) in diethyl etherunder Ar, cooled to -78°C, stirred for 2 h; solvent evapd. in vac., residue washed with n-pentane at -50°C, detd. by 1H NMR, 13C NMR, 31P NMR, MS;
DOI:10.1002/ejic.201200368