1,1,1,3-TETRACHLOROOCTANE

Base Information

• Chemical Name: 1,1,1,3-TETRACHLOROOCTANE
• CAS No.: 18088-13-6
• Molecular Formula: C8H14 Cl4
• Molecular Weight: 252.011
• Hs Code.: 2903199000
• Mol file: 18088-13-6.mol

Synonyms:1,1,1,3-Tetrachlorooctane

Chemical Property of 1,1,1,3-TETRACHLOROOCTANE

Chemical Property:

• Boiling Point: 113 °C(Press: 5 Torr)
• PSA: 0.00000
• Density: 1.220±0.06 g/cm3(Predicted)
• LogP: 4.93440

Purity/Quality:

99%min ^*data from raw suppliers

1,1,1,3-TETRACHLOROOCTANE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,1,1,3-TETRACHLOROOCTANE

There total 11 articles about 1,1,1,3-TETRACHLOROOCTANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

tetrachloromethane (56-23-5) + 1-Heptene (592-76-7) → 1,1,1,3-tetrachlorooctane (18088-13-6)

Guidance literature:

hexacarbonyl molybdenum; In acetonitrile; at 80 ℃; for 23h;

DOI:10.1016/S0022-328X(03)00238-9

Reference yield: 52.0%

1-Heptene (592-76-7) + Trichloromethanesulfonyl chloride (2547-61-7) → 1,1,1,3-tetrachlorooctane (18088-13-6)

Guidance literature:

dichlorotris(triphenylphosphine)ruthenium(II); In benzene; at 140 ℃; for 38h;

Reference yield: 45.0%

tetrachloromethane (56-23-5) + 1-Heptene (592-76-7) → 1,1,1,3-tetrachlorooctane (18088-13-6) + 3-hydroxy-1,1,1-trichlorooctane (1207726-71-3)

Guidance literature:

With chromium(III) acetylacetonate; water; at 170 ℃; for 6h; Autoclave;

DOI:10.1134/S0965544109040136

upstream raw materials:

tetrachloromethane

1-Heptene

Trichloromethanesulfonyl chloride

chloroform

Downstream raw materials:

(E)-oct-2-enoic acid

1,1,3-trichlorooctane

Refernces

• 1、 Bussey, Katherine A.,Cavalier, Annie R.,Mraz, Margaret E.,Oshin, Kayode D.,Sarjeant, Amy,Pintauer, Tomislav. "Synthesis, characterization, X-ray crystallography analysis, and catalytic activity of bis(2-pyridylmethyl)amine copper complexes containing coupled pendent olefinic arms in atom transfer radical addition (ATRA) reactions". . p. 256 - 267. Retrieved 2016.
• 2、 Zorin,Zaynashev,Zorin. "Reaction of Lithium Acylate α-Carbanions with Carbon Tetrachloride". . p. 42 - 46. Retrieved 2019/04/27.
• 3、 Khusnutdinov,Schadneva,Oshnyakova,Dzhemilev. "Addition of CCl4 to olefins catalyzed by chromium and ruthenium complexes: The influence of water as a nucleophilic additive". experimental part. p. 331 - 338. Retrieved 2010/06/16.