Re(CO)₅Au(PPh₃)

Base Information

Chemical Name:Re(CO)₅Au(PPh₃)
CAS No.:20519-22-6
Molecular Formula:C₂₃H₁₅AuO₅PRe
Molecular Weight:785.516
Hs Code.:

Synonyms:Re(CO)₅Au(PPh₃)

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Chemical Property of Re(CO)₅Au(PPh₃)

Chemical Property:

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Technology Process of Re(CO)₅Au(PPh₃)

There total 4 articles about Re(CO)₅Au(PPh₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 14285-68-8
decacarbonyldirhenium⁽⁰⁾

potassium amalgam: potassium amalgam

: 53317-87-6
tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate

: 20519-22-6
Re(CO)₅Au(PPh₃)

: ((C₆H₅)3PAu)4Re(CO)4⁽¹⁺⁾*BF₄^(1-)={((C₆H₅)3PAu)4Re(CO)4}BF₄

: 59030-44-3,324775-26-0
((C₆H₅)3PAu)3Re(CO)4

Guidance literature:: In tetrahydrofuran; stirring of Re2(CO)10 with Na-amalgam (90 min, N2-atmosphere), addn. to suspn. of Au-complex (during 5 min, N2-atmosphere), then 30 min; solvent removal, extn. (Et2O), dissoln. of residue in CH2Cl2, filtration, crystn. on layering with Et2O (-30°C); elem. anal.;
DOI:10.1016/0022-328X(92)80218-M

Reference yield:

: methyl(triphenylphosphine)gold(I)

: 16457-30-0
hydridopentacarbonylrhenium(I)

: 20519-22-6
Re(CO)₅Au(PPh₃)

Guidance literature:: With 2,2'-azobis(isobutyronitrile); In not given; a soln. of Ph2PAuMe, HRe(CO)5 and AIBN was kept at ambient temp. for 36 h or heated at 90°C (stoich. amt. of AIBN); no reaction was observed; NMR monitoring;
DOI:10.1021/ja00265a018

Reference yield:

: 14285-68-8
decacarbonyldirhenium⁽⁰⁾

: methyl(triphenylphosphine)gold(I)

: 16457-30-0
hydridopentacarbonylrhenium(I)

: 25838-69-1,64626-67-1,82443-74-1
[Re(P(C₆H₅)3)(CO)4(H)]

: 20519-22-6
Re(CO)₅Au(PPh₃)

Guidance literature:: With triphenylphosphine; In benzene-d6; Irradiation (UV/VIS); PPh3 was added under N2 to a benzene-d6 soln. of Ph3PAuMe, HRe(CO)5 and Re2(CO)10 prepared under vac., mixt. was irradiated with a 450-W UV broad-band lamp (Pyrex-filtered); only HRe(CO)4PPh3 was formed; (1)H NMR monitoring;
DOI:10.1021/ja00265a018