Diphenyl phosphorochloridite

Base Information

• Chemical Name: Diphenyl phosphorochloridite
• CAS No.: 5382-00-3
• Molecular Formula: C₁₂H₁₀ClO₂P
• Molecular Weight: 252.637
• Mol file: 5382-00-3.mol

Synonyms:Diphenyl phosphorochloridite

Chemical Property of Diphenyl phosphorochloridite

Chemical Property:

• Boiling Point: 165-174 °C(Press: 1 Torr)
• Density: 1.2471 g/cm3

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diphenyl phosphorochloridite

There total 23 articles about Diphenyl phosphorochloridite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

triphenyl phosphite (101-02-0) + chlorobis(o-phenylenedioxy)phosphorane (6857-81-4) → Diphenyl phosphorochloridite (5382-00-3) + 2-phenoxy-2,2'-spirobi<1,3,2λ5-benzodioxaphosphole> (19579-02-3)

Guidance literature:

for 3h; Heating;

Reference yield: 63.6%

chlorotriphenoxy(trichloroacetyl)phosphorane (73569-84-3) → triphenyl phosphite (101-02-0) + Diphenyl phosphorochloridite (5382-00-3) + trifluoroacetyl chloride (76-02-8)

Guidance literature:

at 50 ℃; under 10 Torr; Mechanism;

Reference yield: 40.0%

triphenyl phosphite (101-02-0) → Diphenyl phosphorochloridite (5382-00-3)

Guidance literature:

With acetic acid; phosphorus trichloride; at 80 ℃; for 12h; Inert atmosphere;

DOI:10.1021/acs.orglett.7b01420

upstream raw materials:

triphenyl phosphite

benzenesulfonyl chloride

benzene

phenol

Downstream raw materials:

phosphorous acid-(2-ethyl-hexyl ester)-diphenyl ester

phosphorous acid biphenyl-4-yl ester-diphenyl ester

diphenyl ethylphosphonite

isopropyl-diphenoxy-phosphine

Refernces

• 1、 -. "Selective synthesis of organophosphites". Page 6. . Retrieved 2008/06/13.
• 2、 Chauzov, V. A.,Studnev, Yu. N.,Ragulin, L. I.,Fokin, A. V.. "FACTORS DETERMINING THE POSITION OF EQUILIBRIUM IN SYSTEMS OF PHOSPHORUS(III) ESTERS OR THIOESTERS AND CORRESPONDING ACID HALIDES AND HALIDITES". . p. 1146 - 1148. Retrieved 2007/10/02.