Diethoxy-sulfanylidene-sulfido-lambda5-phosphane;nickel(2+)

Base Information

• Chemical Name: Diethoxy-sulfanylidene-sulfido-lambda5-phosphane;nickel(2+)
• CAS No.: 16743-23-0
• Molecular Formula: C₈H₂₀NiO₄P₂S₄
• Molecular Weight: 429.146
• Mol file: 16743-23-0.mol

Synonyms:

Chemical Property of Diethoxy-sulfanylidene-sulfido-lambda5-phosphane;nickel(2+)

Chemical Property:

• Vapor Pressure: 0.0887mmHg at 25°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 8
• Exact Mass: 427.907309
• Heavy Atom Count: 19
• Complexity: 248

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCOP(=S)(OCC)[S-].CCOP(=S)(OCC)[S-].[Ni+2]

Technology Process of Diethoxy-sulfanylidene-sulfido-lambda5-phosphane;nickel(2+)

There total 11 articles about Diethoxy-sulfanylidene-sulfido-lambda5-phosphane;nickel(2+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

nickel(II) chloride hexahydrate + ethanol (64-17-5) + phosphorous (V) sulfide → bis(O,O'-diethyldithiophosphato-S,S')nickel(II) (16743-23-0)

Guidance literature:

In ethanol; dissolving nickel compd. and P2S5 in C2H5OH, heating under reflux for 1 h; cooling to room temp., evapn., crystn. from CH2Cl2/C2H5OH (1:1), elem. anal.;

DOI:10.1039/b819326f

Reference yield: 73.0%

[Ni(S2P(OEt)2)2(CN-2,6-dimethylphenyl)2] (701203-71-6) + tricyclohexylphosphine (2622-14-2) → nickel(II) bis(O,O'-diethyl dithiophosphate) (16743-23-0) + [Ni(S2P(O)(OEt))(CN-2,6-dimethylphenyl)2] (701203-73-8)

Guidance literature:

In dichloromethane; (N2); P(C6H11)3 (1 equiv.) was added to soln. of Ni complex in CH2Cl2; mixt. was stirred at room temp. for 10 h; solvent evapd. (vac.); washed (hexane); redissolved in CH2Cl2/hexane (1/1); chromd. (silica, CH2Cl2/hexane, 1/1, THF); hexane added; slowly evapd.; elem. anal.;

DOI:10.1021/om0343364

Reference yield: 49.0%

antimony(III) tris(O,O-diethyl phosphorodithioate) (74153-83-6,875827-00-2) + nickel dichloride (83864-14-6) → nickel(II) bis(O,O'-diethyl dithiophosphate) (16743-23-0)

Guidance literature:

In tetrahydrofuran; byproducts: SbCl3; Ar; refluxed; 10 h;; filtered; evapd.; crystd. from Skelly F solvent;; Kinetics;

upstream raw materials:

nickel

O,O-Diethyl hydrogen phosphorodithioate

nickel diacetate

ethanol

Downstream raw materials:

nickel(II) iodide

bis(diethoxyphosphoryl)disulphide

sodium diethyl phosphate

[(1,2-bis(diphenylphosphino)methane)(O,O'-diethyldithiophosphate)nickel(II)] perchlorate hydrate

Refernces

• 1、 Yadav, Reena,Singh, Ashish Kumar,Waghadkar, Yogesh,Kociok-K?hn, Gabriele,Kumar, Abhinav,Chauhan, Ratna,Rane, Sunit,Gosavi, Suresh. "1,2-Bis(diphenylphosphino)ethane nickel(ii) O,O′-dialkyldithiophosphates as potential precursors for nickel sulfides". . p. 1327 - 1333. Retrieved 2017.
• 2、 Geloso, Corrado,Kumar, Rajesh,Lopez-Grado, Jaime Romero,Tuck, Dennis G.. "THE DIRECT ELECTROCHEMICAL SYNTHESIS OF DIALKYLDITHIOCARBAMATE AND DIETHYLDITHIOPHOSPHATE COMPLEXES OF MAIN GROUP AND TRANSITION METALS". . p. 928 - 932. Retrieved 2007/10/02.