[Re(C(O)C₆H₂(CH₃)3)(CO)5]

Base Information

Chemical Name:[Re(C(O)C₆H₂(CH₃)3)(CO)5]
CAS No.:155941-72-3
Molecular Formula:C₁₅H₁₁O₆Re
Molecular Weight:473.456
Hs Code.:

[Re(C(O)C<sub>6</sub>H<sub>2</sub>(CH<sub>3</sub>)3)(CO)5]

Synonyms:[Re(C(O)C₆H₂(CH₃)3)(CO)5]

Suppliers and Price of [Re(C(O)C₆H₂(CH₃)3)(CO)5]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Re(C(O)C₆H₂(CH₃)3)(CO)5]

Chemical Property:

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Technology Process of [Re(C(O)C₆H₂(CH₃)3)(CO)5]

There total 1 articles about [Re(C(O)C₆H₂(CH₃)3)(CO)5] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 14285-68-8
decacarbonyldirhenium⁽⁰⁾

: 938-18-1
mesitylene-2-carboxylic acid chloride

: 155941-72-3
[Re(C(O)C₆H₂(CH₃)3)(CO)5]

Guidance literature:: With sodium amalgam; In tetrahydrofuran; diethyl ether; reaction under inert gas: addn. of Re2(CO)10 to freshly prepared Na#Hg in ether containing THF, shaking for 5 min, stirring overnight, decanting, filtn., concn. the volume, addn. of the benzoyl chloride; filtn. after 1 h, removal of solvent from filtrate, extn. with pentane,filtn., removal of solvent under vac., dissolving in CH2Cl2, passing through activated alumina, removal of solvent under vac., recrystn. from pentane at -40°C, elem. anal.;
DOI:10.1021/om00017a080

Reference yield: 95.0%

: 155941-72-3
[Re(C(O)C₆H₂(CH₃)3)(CO)5]

: 75-09-2
dichloromethane

: 358-23-6
trifluoromethylsulfonic anhydride

: 180776-52-7
ReCl(CO)4(CC₆H₂(CH₃)3)⁽¹⁺⁾*O₃SCF₃^(1-) = [ReCl(CO)4(CC₆H₂(CH₃)3)]O₃SCF₃

Guidance literature:: In dichloromethane; (N2); addn. of (CF3SO2)2O in CH2Cl2 with rapid stirring to a -40°C cold soln. of the Re complex in CH2Cl2, stirring (30 min); solvent removal, washing (toluene; light petroleum);
DOI:10.1039/DT9960002827