bis(O-2,4-di-tert-butylphenyl(4-methoxyphenyldithiophosphonato)-κS,S')nickel(II)

Base Information

• Chemical Name: bis(O-2,4-di-tert-butylphenyl(4-methoxyphenyldithiophosphonato)-κS,S')nickel(II)
• CAS No.: 466692-66-0
• Molecular Formula: C₄₂H₅₆NiO₄P₂S₄
• Molecular Weight: 873.806
• Mol file: 466692-66-0.mol

Synonyms:bis(O-2,4-di-tert-butylphenyl(4-methoxyphenyldithiophosphonato)-κS,S')nickel(II)

Chemical Property of bis(O-2,4-di-tert-butylphenyl(4-methoxyphenyldithiophosphonato)-κS,S')nickel(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(O-2,4-di-tert-butylphenyl(4-methoxyphenyldithiophosphonato)-κS,S')nickel(II)

There total 2 articles about bis(O-2,4-di-tert-butylphenyl(4-methoxyphenyldithiophosphonato)-κS,S')nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-bis(O-2,4-di-tert-butylphenyl(4-methoxyphenyldithiophosphonato)-κS,S')bis(3-acetylpyridine-κN)nickel(II) → methyl-3-pyridylketone (350-03-8) + bis(O-2,4-di-tert-butylphenyl(4-methoxyphenyldithiophosphonato)-κS,S')nickel(II) (466692-66-0)

Guidance literature:

In neat (no solvent, solid phase); by standing for several wk;

DOI:10.1002/zaac.200400053

Reference yield:

nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) + O-2,4-di-tert-butylphenyl (4-methoxyphenyl)dithiophosphonate (466692-67-1) → trans-bis[O-2,4-di-tert-butylphenyl(4-methoxyphenyl)dithiophosphonato-κ2S,S']nickel(II) (466692-66-0)

Guidance literature:

In acetic acid; benzene; phosphonate and nickel acetate in benzene/CH3COOH (1/1); crystn. from reaction mixt.;

DOI:10.1107/S0108270102008764

Reference yield: 54.0%

methyl-3-pyridylketone (350-03-8) + bis(O-2,4-di-tert-butylphenyl(4-methoxyphenyldithiophosphonato)-κS,S')nickel(II) (466692-66-0) → trans-bis(O-2,4-di-tert-butylphenyl(4-methoxyphenyldithiophosphonato)-κS,S')bis(3-acetylpyridine-κN)nickel(II)

Guidance literature:

In ethanol; dichloromethane; Ni compd. dissolved in CH2Cl2, excess of N compd. in EtOH added, refluxed until soln. turned green; solvent evapd. at room temp. until 2-3 ml of soln. remained, crystd., dried in vac. and washed with Et2O; elem. anal.;

DOI:10.1002/zaac.200400053

upstream raw materials:

nickel diacetate

O-2,4-di-tert-butylphenyl (4-methoxyphenyl)dithiophosphonate