Ethyl 2-(Chloromethyl)acrylate

Base Information

Chemical Name:Ethyl 2-(Chloromethyl)acrylate
CAS No.:17435-77-7
Molecular Formula:C6H9ClO2
Molecular Weight:148.589
Hs Code.:2916190090
European Community (EC) Number:679-662-3
DSSTox Substance ID:DTXSID60454166
Nikkaji Number:J807.327I
Wikidata:Q72473673
Mol file:17435-77-7.mol

Synonyms:17435-77-7;2-(Chloromethyl)acrylic Acid Ethyl Ester;Ethyl 2-(Chloromethyl)acrylate;Ethyl 2-(chloromethyl)prop-2-enoate;2-Propenoic acid, 2-(chloromethyl)-, ethyl ester;Ethyl 2-(Chloromethyl)acrylate (stabilized with HQ);ethyl 2-chloromethylacrylate;Ethyl2-(Chloromethyl)acrylate;ethyl alpha-chloromethylacrylate;SCHEMBL1483885;Ethyl-2-(chloromethyl)-acrylate;DTXSID60454166;KPXRGIVPSXFJEX-UHFFFAOYSA-N;MFCD01321155;AKOS006222559;2-chloromethyl acrylic acid ethyl ester;BS-43913;CS-0215923;FT-0737917;EN300-310431;T70430;2-(Chloromethyl)acrylic acid ethyl ester (stabilized with HQ)

Suppliers and Price of Ethyl 2-(Chloromethyl)acrylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Ethyl2-Chloromethylacrylate
1g
$ 745.00

TCI Chemical
Ethyl 2-(Chloromethyl)acrylate (stabilized with HQ) >98.0%(GC)
1g
$ 215.00

Crysdot
Ethyl2-(chloromethyl)acrylate 95+%
5g
$ 517.00

American Custom Chemicals Corporation
2-(CHLOROMETHYL)ACRYLIC ACID ETHYL ESTER 95.00%
5MG
$ 499.27

AK Scientific
2-(Chloromethyl)acrylicacidethylester
1g
$ 372.00

Total 24 raw suppliers

Chemical Property of Ethyl 2-(Chloromethyl)acrylate

Chemical Property:

Vapor Pressure:1.206mmHg at 25°C
Refractive Index:1.438
Boiling Point:174.432 °C at 760 mmHg
Flash Point:67.127 °C
PSA：26.30000
Density:1.082 g/cm³
LogP:1.34450
Storage Temp.:Refrigerator
XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:148.0291072
Heavy Atom Count:9
Complexity:120

Purity/Quality:

99%, ^*data from raw suppliers

Ethyl2-Chloromethylacrylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C(=C)CCl
Uses Ethyl 2-Chloromethylacrylate has been used in reactions with allyl bromide (A549655) and α-amino-ε-caprolactam to prepare the diacrylate/diallyl derivatives of α-amino-ε-caprolactam.

Technology Process of Ethyl 2-(Chloromethyl)acrylate

There total 5 articles about Ethyl 2-(Chloromethyl)acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 10029-04-6
ethyl 2-(hydroxymethyl)acrylate

: 17435-77-7
ethyl 2-(chloromethyl)acrylate

Guidance literature:: With thionyl chloride; In N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; at 20 ℃; for 3h;
DOI:10.1055/s-1982-29998

Reference yield:

: 20605-01-0
diethyl bis(hydroxymethyl)malonate

: 17435-77-7
ethyl 2-(chloromethyl)acrylate

: 10029-04-6
ethyl 2-(hydroxymethyl)acrylate

Guidance literature:: With hydrogenchloride; Erwaermen des Reaktionsprodukts mit Aethanol, Benzol und wenig Schwefelsaeure unter Entfernen des entstehenden Wassers;
DOI:10.1021/jo01124a011

Reference yield:

: 140-88-5,9003-32-1
ethyl acrylate

: 17435-77-7
ethyl 2-(chloromethyl)acrylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1,8-diazabicyclo[5.4.0]undec-7-ene / tetrahydrofuran; water / 6 h / 20 °C

2: thionyl chloride / toluene / 9 h / 20 °C

With thionyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; water; toluene;