[cerium(III)(dicyclohexylamido)3(tetrahydrofuran)]*PhMe

Base Information

• Chemical Name: [cerium(III)(dicyclohexylamido)3(tetrahydrofuran)]*PhMe
• CAS No.: 912454-59-2
• Molecular Formula: C₇H₈*C₄₀H₇₄CeN₃O
• Molecular Weight: 845.308
• Mol file: 912454-59-2.mol

Synonyms:[cerium(III)(dicyclohexylamido)3(tetrahydrofuran)]*PhMe

Chemical Property of [cerium(III)(dicyclohexylamido)3(tetrahydrofuran)]*PhMe

Chemical Property:

Purity/Quality:

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Technology Process of [cerium(III)(dicyclohexylamido)3(tetrahydrofuran)]*PhMe

There total 1 articles about [cerium(III)(dicyclohexylamido)3(tetrahydrofuran)]*PhMe which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + cerium chloride (7790-86-5,15785-07-6) + lithium dicyclohexylamide (4111-55-1) + toluene (108-88-3,15644-74-3,16713-13-6) → [cerium(III)(dicyclohexylamido)3(tetrahydrofuran)]*PhMe (912454-59-2)

Guidance literature:

In tetrahydrofuran; exclusion of air; CeCl3 stirred with thf at room temp. for 2 d, suspn. of solvate obtained; soln. of LiNCy2 (2.7 equiv.) in thf added slowly at 0°C, stirred at room temp. for 1 h; solvent removed under vac., residue extd. twice with toluene, filtered, filtrate concd., covered with hexanes, stored at -27°C for 2 d;

DOI:10.1039/b607429d

Reference yield: 35.0%

[cerium(III)(dicyclohexylamido)3(tetrahydrofuran)]*PhMe (912454-59-2) → cerium(IV) tetra(dicyclohexylamide)*toluene

Guidance literature:

With air; In toluene; Schlenk techniques; dry air introduced into soln. of Ce(III) complex in degassed toluene, mixt. stirred at 25°C for 1 h; stored at 5°C overnight, black crystals washed by decantation with cold toluene, dried;

DOI:10.1039/b607429d

upstream raw materials:

tetrahydrofuran

cerium chloride

lithium dicyclohexylamide

toluene