(1,1-dimethylethyl)dimethylsilyl 1-methoxy-1-phenylmethyl peroxide

Base Information

• Chemical Name: (1,1-dimethylethyl)dimethylsilyl 1-methoxy-1-phenylmethyl peroxide
• CAS No.: 295357-38-9
• Molecular Formula: C₁₄H₂₄O₃Si
• Molecular Weight: 268.428
• Mol file: 295357-38-9.mol

Synonyms:(1,1-dimethylethyl)dimethylsilyl 1-methoxy-1-phenylmethyl peroxide

Chemical Property of (1,1-dimethylethyl)dimethylsilyl 1-methoxy-1-phenylmethyl peroxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,1-dimethylethyl)dimethylsilyl 1-methoxy-1-phenylmethyl peroxide

There total 3 articles about (1,1-dimethylethyl)dimethylsilyl 1-methoxy-1-phenylmethyl peroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(2-methoxyvinyl)benzene (4747-15-3) → (1,1-dimethylethyl)dimethylsilyl 1-methoxy-1-phenylmethyl peroxide (295357-38-9)

Guidance literature:

Multi-step reaction with 2 steps

1: O₃; O₂ / methanol; CH₂Cl₂ / -78 °C

2: imidazole / CH₂Cl₂; dimethylformamide

With 1H-imidazole; oxygen; ozone; In methanol; dichloromethane; N,N-dimethyl-formamide;

DOI:10.1021/jo991714z

Reference yield:

benzaldehyde (100-52-7) → (1,1-dimethylethyl)dimethylsilyl 1-methoxy-1-phenylmethyl peroxide (295357-38-9)

Guidance literature:

Multi-step reaction with 3 steps

1.1: tetrahydrofuran / 0.17 h / 0 °C

1.2: 68 percent / tetrahydrofuran / 1 h / 0 °C

2.1: O₃; O₂ / methanol; CH₂Cl₂ / -78 °C

3.1: imidazole / CH₂Cl₂; dimethylformamide

With 1H-imidazole; oxygen; ozone; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;

DOI:10.1021/jo991714z

Reference yield:

1-methoxy-1-hydroperoxy-methylbenzene (10027-71-1) + tert-butyldimethylsilyl chloride (18162-48-6) → (1,1-dimethylethyl)dimethylsilyl 1-methoxy-1-phenylmethyl peroxide (295357-38-9)

Guidance literature:

With 1H-imidazole; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.1021/jo991714z

upstream raw materials:

1-methoxy-1-hydroperoxy-methylbenzene

tert-butyldimethylsilyl chloride

1-(2-methoxyvinyl)benzene

benzaldehyde

Downstream raw materials:

4-methoxy-4-phenyl-1-butene

ethyl-2-methyl-3-[(t-butyldimethylsilyl)dioxy]-3-phenylpropionate

Refernces