2,2,5-trimethyl-3-(1-(4'-chloromethyl)phenylethoxy)-4-(3'-(trimethylsilyl)ethynyl)phenyl-3-azahexane

Base Information

Chemical Name:2,2,5-trimethyl-3-(1-(4'-chloromethyl)phenylethoxy)-4-(3'-(trimethylsilyl)ethynyl)phenyl-3-azahexane
CAS No.:1239684-42-4
Molecular Formula:C₂₈H₄₀ClNOSi
Molecular Weight:470.17
Hs Code.:

Synonyms:2,2,5-trimethyl-3-(1-(4'-chloromethyl)phenylethoxy)-4-(3'-(trimethylsilyl)ethynyl)phenyl-3-azahexane

Suppliers and Price of 2,2,5-trimethyl-3-(1-(4'-chloromethyl)phenylethoxy)-4-(3'-(trimethylsilyl)ethynyl)phenyl-3-azahexane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,2,5-trimethyl-3-(1-(4'-chloromethyl)phenylethoxy)-4-(3'-(trimethylsilyl)ethynyl)phenyl-3-azahexane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,2,5-trimethyl-3-(1-(4'-chloromethyl)phenylethoxy)-4-(3'-(trimethylsilyl)ethynyl)phenyl-3-azahexane

There total 4 articles about 2,2,5-trimethyl-3-(1-(4'-chloromethyl)phenylethoxy)-4-(3'-(trimethylsilyl)ethynyl)phenyl-3-azahexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.6%

: 1239684-41-3
2,2,5-trimethyl-4-(3'-(trimethylsilyl)ethynyl)phenyl-3-azahexane-3-nitroxide

: 1592-20-7,29296-32-0
4-Vinylbenzyl chloride

: 1239684-42-4
2,2,5-trimethyl-3-(1-(4'-chloromethyl)phenylethoxy)-4-(3'-(trimethylsilyl)ethynyl)phenyl-3-azahexane

Guidance literature:: 2,2,5-trimethyl-4-(3'-(trimethylsilyl)ethynyl)phenyl-3-azahexane-3-nitroxide; 4-Vinylbenzyl chloride; With (-)-chloro((1R,2R)-4,4',6,6'-tetra-tert-butyl-2,2'-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato)manganese(III); di-tert-butyl peroxide; In ethanol; toluene; for 0.166667h; Inert atmosphere;

With sodium tetrahydroborate; In ethanol; toluene; for 18h; Inert atmosphere;
DOI:10.1002/pola.24126

Reference yield:

: 85664-55-7
N-(tert-Butyl)-2-methylpropylidenamin-N-oxid

: 1239684-42-4
2,2,5-trimethyl-3-(1-(4'-chloromethyl)phenylethoxy)-4-(3'-(trimethylsilyl)ethynyl)phenyl-3-azahexane

Guidance literature:: Multi-step reaction with 3 steps

1.1: magnesium / tetrahydrofuran / 1.5 h / Reflux

1.2: 3 h / Reflux

2.1: ammonium hydroxide; copper(II) acetate monohydrate / tetrahydrofuran; methanol / 2 h

3.1: (-)-chloro((1R,2R)-4,4',6,6'-tetra-tert-butyl-2,2'-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato)manganese(III); di-tert-butyl peroxide / ethanol; toluene / 0.17 h / Inert atmosphere

3.2: 18 h / Inert atmosphere

With ammonium hydroxide; (-)-chloro((1R,2R)-4,4',6,6'-tetra-tert-butyl-2,2'-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato)manganese(III); di-tert-butyl peroxide; copper(II) acetate monohydrate; magnesium; In tetrahydrofuran; methanol; ethanol; toluene;
DOI:10.1002/pola.24126

Reference yield:

: 3989-13-7
2-(3-bromophenyl)ethynyltrimethylsilane

: 1239684-42-4
2,2,5-trimethyl-3-(1-(4'-chloromethyl)phenylethoxy)-4-(3'-(trimethylsilyl)ethynyl)phenyl-3-azahexane

Guidance literature:: Multi-step reaction with 3 steps

1.1: magnesium / tetrahydrofuran / 1.5 h / Reflux

1.2: 3 h / Reflux

2.1: ammonium hydroxide; copper(II) acetate monohydrate / tetrahydrofuran; methanol / 2 h

3.1: (-)-chloro((1R,2R)-4,4',6,6'-tetra-tert-butyl-2,2'-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato)manganese(III); di-tert-butyl peroxide / ethanol; toluene / 0.17 h / Inert atmosphere

3.2: 18 h / Inert atmosphere

With ammonium hydroxide; (-)-chloro((1R,2R)-4,4',6,6'-tetra-tert-butyl-2,2'-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato)manganese(III); di-tert-butyl peroxide; copper(II) acetate monohydrate; magnesium; In tetrahydrofuran; methanol; ethanol; toluene;
DOI:10.1002/pola.24126