(3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-2-methylene-pentane-1,3-diol

Base Information

Chemical Name:(3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-2-methylene-pentane-1,3-diol
CAS No.:216449-79-5
Molecular Formula:C₂₃H₃₂O₃Si
Molecular Weight:384.591
Hs Code.:

Synonyms:(3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-2-methylene-pentane-1,3-diol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-2-methylene-pentane-1,3-diol

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Technology Process of (3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-2-methylene-pentane-1,3-diol

There total 1 articles about (3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-2-methylene-pentane-1,3-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: ((2S,3S)-3-((S)-1-((1,1-dimethylethyl)diphenylsilyloxy)propan-2-yl)-2-methyloxiran-2-yl)methanol

: 216449-79-5
(3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-2-methylene-pentane-1,3-diol

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; at 0 - 24 ℃;
DOI:10.1039/a804954h

Reference yield:

: 545-06-2
trichloroacetonitrile

: 216449-79-5
(3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-2-methylene-pentane-1,3-diol

: 216449-81-9
2,2,2-Trichloro-acetimidic acid (3S,4S)-5-(tert-butyl-diphenyl-silanyloxy)-3-hydroxy-4-methyl-2-methylene-pentyl ester

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In various solvent(s); at -78 ℃;
DOI:10.1039/a804954h

Reference yield:

: 216449-79-5
(3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-2-methylene-pentane-1,3-diol

: 216449-85-3
(1S,2S)-3-(tert-Butyl-diphenyl-silanyloxy)-2-methyl-1-[4-(2,2,6,6-tetramethyl-piperidin-1-yloxymethyl)-2-trichloromethyl-4,5-dihydro-oxazol-4-yl]-propan-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: DBU / various solvent(s) / -78 °C

2: 1.) Hg(O₂CCF₃)2, K₂CO₃, KBr, H₂O, 2.) LiBH₄ / 1.) THF, 0 deg C, 2.) THF, 24 deg C

With lithium borohydride; water; mercury(II) trifluoroacetate; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; potassium bromide; In various solvent(s);
DOI:10.1039/a804954h