H₂-5,15-di(p-methoxycarbonylphenyl)-10,20-di(p-tolyl)porphyrin

Base Information

• Chemical Name: H₂-5,15-di(p-methoxycarbonylphenyl)-10,20-di(p-tolyl)porphyrin
• CAS No.: 57056-44-7
• Molecular Formula: C₅₀H₃₈N₄O₄
• Molecular Weight: 758.876
• Mol file: 57056-44-7.mol

Synonyms:H₂-5,15-di(p-methoxycarbonylphenyl)-10,20-di(p-tolyl)porphyrin

Chemical Property of H₂-5,15-di(p-methoxycarbonylphenyl)-10,20-di(p-tolyl)porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of H₂-5,15-di(p-methoxycarbonylphenyl)-10,20-di(p-tolyl)porphyrin

There total 5 articles about H₂-5,15-di(p-methoxycarbonylphenyl)-10,20-di(p-tolyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

pyrrole (109-97-7,30604-81-0) + p-Anisaldehyde dimethyl acetal (2186-92-7) + 4-methyl-benzaldehyde (104-87-0) → H2-5,15-di(p-methoxycarbonylphenyl)-10,20-di(p-tolyl)porphyrin (57056-44-7) + 5,10,15-tris(4-methylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (57105-80-3) + 5,10,15,20-tetra(p-tolyl)porphyrin (14527-51-6) + 5,10-bis(4-methoxycarbonylphenyl)-15,20-bis(4-methylphenyl)porphyrin

Guidance literature:

With propionic acid; 1.) reflux, 1 h, 2.) 5 deg C, 24 h;

DOI:10.1016/S0040-4020(01)86323-7

Reference yield: 5.0%

4-methyl-benzaldehyde (104-87-0) + 5-(4-carbomethoxyphenyl)dipyrromethane (167482-99-7) → H2-5,15-di(p-methoxycarbonylphenyl)-10,20-di(p-tolyl)porphyrin (57056-44-7)

Guidance literature:

4-methyl-benzaldehyde; 5-(4-carbomethoxyphenyl)dipyrromethane; In chloroform; for 1h; Inert atmosphere;

With boron trifluoride diethyl etherate; In chloroform; for 2h; Further stages; Darkness; Inert atmosphere;

DOI:10.1039/c002757j

Reference yield: 4.1%

4-methyl-benzaldehyde (104-87-0) + meso-(4-pyridyl)-2,2'-dipyrromethane (52073-75-3) + 5-(4-carbomethoxyphenyl)dipyrromethane (167482-99-7) → H2-5,15-di(p-methoxycarbonylphenyl)-10,20-di(p-tolyl)porphyrin (57056-44-7) + 5,15-bis(4-methyl)phenyl-10-(4-pyridyl)-20-(4-formatemethyl)phenyl porphyrin

Guidance literature:

In propionic acid; for 2.5h; Reflux;

DOI:10.1039/b902408p

upstream raw materials:

pyrrole

p-Anisaldehyde dimethyl acetal

4-methyl-benzaldehyde

meso-(4-pyridyl)-2,2'-dipyrromethane

Downstream raw materials:

4-[(5Z,10Z,14Z,19Z)-15-(4-Chlorocarbonyl-phenyl)-10,20-di-p-tolyl-porphyrin-5-yl]-benzoic acid methyl ester

5-(4-carboxyphenyl)-15-(4-carbomethoxyphenyl)-10,20-bis(4-methylphenyl)porphyrin