(1R,2S)-1-(E)-N-phenylmethyleneamino-2-vinylcyclopropanecarboxylic acid ethyl ester

Base Information

Chemical Name:(1R,2S)-1-(E)-N-phenylmethyleneamino-2-vinylcyclopropanecarboxylic acid ethyl ester
CAS No.:1225330-50-6
Molecular Formula:C₁₅H₁₇NO₂
Molecular Weight:243.305
Hs Code.:

Synonyms:(1R,2S)-1-(E)-N-phenylmethyleneamino-2-vinylcyclopropanecarboxylic acid ethyl ester

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Chemical Property of (1R,2S)-1-(E)-N-phenylmethyleneamino-2-vinylcyclopropanecarboxylic acid ethyl ester

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Technology Process of (1R,2S)-1-(E)-N-phenylmethyleneamino-2-vinylcyclopropanecarboxylic acid ethyl ester

There total 6 articles about (1R,2S)-1-(E)-N-phenylmethyleneamino-2-vinylcyclopropanecarboxylic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 821-06-7
(E)-1,4-dibromobutene

: 133038-44-5
[(benzylidene)amino]acetic acid ethyl ester

: 1225330-50-6
(1R,2S)-1-(E)-N-phenylmethyleneamino-2-vinylcyclopropanecarboxylic acid ethyl ester

Guidance literature:: [(benzylidene)amino]acetic acid ethyl ester; With N-[2,5-bis(trifluoromethyl)benzyl]cinchonidinium bromide; In toluene; at -1 ℃; for 0.0833333h; Inert atmosphere;

(E)-1,4-dibromobutene; With water; sodium hydroxide; In toluene; at 0 ℃; for 22h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/op100070d

Reference yield: 6.0%

: 821-06-7
(E)-1,4-dibromobutene

: 133038-44-5
[(benzylidene)amino]acetic acid ethyl ester

: 7-phenyl-6,7-dihydro-1H-azepine-2-carboxylic acid ethyl ester

: (1S,2R)-1-(E)-N-phenylmethyleneamino-2-vinylcyclopropanecarboxylic acid ethyl ester

: 1225330-50-6
(1R,2S)-1-(E)-N-phenylmethyleneamino-2-vinylcyclopropanecarboxylic acid ethyl ester

Guidance literature:: [(benzylidene)amino]acetic acid ethyl ester; With N-[2,5-bis(trifluoromethyl)benzyl]cinchonidinium bromide; In toluene; at 0 ℃; for 0.5h; Inert atmosphere;

(E)-1,4-dibromobutene; With water; sodium hydroxide; In toluene; at -3 - 1 ℃; for 20h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/op100070d

Reference yield:

: 821-06-7
(E)-1,4-dibromobutene

: 133038-44-5
[(benzylidene)amino]acetic acid ethyl ester

: 7-phenyl-6,7-dihydro-1H-azepine-2-carboxylic acid ethyl ester

: 1225330-50-6
(1R,2S)-1-(E)-N-phenylmethyleneamino-2-vinylcyclopropanecarboxylic acid ethyl ester

Guidance literature:: With (S)-2,10-di-t-butyl-3,9-dimethoxy-6-methyl-6-(1-methyl-2-methoxy-2,2-di-p-tolylethyl)-4,8-bis(3,5-bistrifluoromethylphenyl)-6,7-dihydro-5H-dibenzo[c,e]azepinium bromide; potassium hydroxide; In water; toluene; at 0 ℃; for 20h; Reagent/catalyst;