O-4-bromophenyl phenyl phenyl(phenyl)phosphinate

Base Information

• Chemical Name: O-4-bromophenyl phenyl phenyl(phenyl)phosphinate
• CAS No.: 21713-54-2
• Molecular Formula: C₁₈H₁₄BrO₂P
• Molecular Weight: 373.186
• Mol file: 21713-54-2.mol

Synonyms:O-4-bromophenyl phenyl phenyl(phenyl)phosphinate

Chemical Property of O-4-bromophenyl phenyl phenyl(phenyl)phosphinate

Chemical Property:

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Technology Process of O-4-bromophenyl phenyl phenyl(phenyl)phosphinate

There total 8 articles about O-4-bromophenyl phenyl phenyl(phenyl)phosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

4-bromo-phenol (106-41-2) + Diphenylphosphine oxide (4559-70-0) → O-4-bromophenyl phenyl phenyl(phenyl)phosphinate (21713-54-2)

Guidance literature:

With methyl-triphenylphosphonium iodide; caesium carbonate; In chloroform; at 20 ℃; for 1h;

DOI:10.1002/ejoc.202000385

Reference yield: 86.0%

diphenyl-phosphinic acid (1707-03-5) + 4-Bromophenylboronic acid (5467-74-3) → O-4-bromophenyl phenyl phenyl(phenyl)phosphinate (21713-54-2)

Guidance literature:

With oxygen; urea; copper(I) bromide; In acetonitrile; at 80 ℃; for 12h; Molecular sieve; Schlenk technique;

Reference yield: 67.0%

4-bromo-phenol (106-41-2) + diphenylphosphane (829-85-6) → O-4-bromophenyl phenyl phenyl(phenyl)phosphinate (21713-54-2)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; caesium carbonate; In acetonitrile; at 20 ℃; for 4h; Electrochemical reaction;

DOI:10.1002/chem.202102262

upstream raw materials:

4-nitrophenyl diphenylphosphinate

p-bromophenoxide ion

4-bromo-phenol

Diphenylphosphinic chloride