tethered (S,S)-MsDPEN

Base Information

• Chemical Name: tethered (S,S)-MsDPEN
• CAS No.: 1245811-48-6
• Molecular Formula: C₂₄H₃₀N₂O₂S
• Molecular Weight: 410.58
• Mol file: 1245811-48-6.mol

Synonyms:tethered (S,S)-MsDPEN

Chemical Property of tethered (S,S)-MsDPEN

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tethered (S,S)-MsDPEN

There total 2 articles about tethered (S,S)-MsDPEN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1S,2S)-N-methanesulfonyl-1,2-diphenylethane-1,2-diamine (300345-76-0) + C10H13F3O3S → tethered (S,S)-MsDPEN (1245811-48-6)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 22 ℃; for 21h;

DOI:10.1002/adsc.201200362 DOI:10.1002/adsc.201200362

Reference yield:

3-(cyclohexa-1,4-dien-1-yl)propan-1-ol (87151-66-4) → tethered (S,S)-MsDPEN (1245811-48-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 2,6-dimethylpyridine / dichloromethane / 1.5 h / 0 - 22 °C / Inert atmosphere

2: triethylamine / dichloromethane / 21 h / 0 - 22 °C

With 2,6-dimethylpyridine; triethylamine; In dichloromethane;

DOI:10.1002/adsc.201200362 DOI:10.1002/adsc.201200362

Reference yield:

tethered (S,S)-MsDPEN (1245811-48-6) → C24H30N2O2S*ClH

Guidance literature:

With hydrogenchloride; In methanol; tert-butyl methyl ether; at 0 ℃; for 0.75h;

DOI:10.1002/adsc.201200362 DOI:10.1002/adsc.201200362

upstream raw materials:

3-(cyclohexa-1,4-dien-1-yl)propan-1-ol

(1S,2S)-N-methanesulfonyl-1,2-diphenylethane-1,2-diamine