Dimethyl 2-(4-methoxybenzyl)malonate

Base Information

Chemical Name:Dimethyl 2-(4-methoxybenzyl)malonate
CAS No.:15378-09-3
Molecular Formula:C13H16 O5
Molecular Weight:252.267
Hs Code.:2918990090
European Community (EC) Number:681-042-2
DSSTox Substance ID:DTXSID90502841
Nikkaji Number:J1.985.492B
Wikidata:Q82356200
Mol file:15378-09-3.mol

Synonyms:15378-09-3;DIMETHYL 2-(4-METHOXYBENZYL)MALONATE;dimethyl 2-[(4-methoxyphenyl)methyl]propanedioate;1,3-DIMETHYL 2-[(4-METHOXYPHENYL)METHYL]PROPANEDIOATE;SCHEMBL5918555;DTXSID90502841;AKOS025396913;AS-62971;DIMETHYL2-(4-METHOXYBENZYL)MALONATE;CS-0337089;Dimethyl [(4-methoxyphenyl)methyl]propanedioate

Suppliers and Price of Dimethyl 2-(4-methoxybenzyl)malonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
DIMETHYL-2-(4-METHOXYBENZYL)MALONATE 95.00%
5MG
$ 501.58

Alfa Aesar
Dimethyl (4-methoxybenzyl)malonate, 95%
5g
$ 189.00

Alfa Aesar
Dimethyl (4-methoxybenzyl)malonate, 95%
1g
$ 58.90

Total 10 raw suppliers

Chemical Property of Dimethyl 2-(4-methoxybenzyl)malonate

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Refractive Index:1.499
Boiling Point:335°Cat760mmHg
PKA:12.43±0.59(Predicted)
Flash Point:145.2°C
PSA：61.83000
Density:1.148g/cm³
LogP:1.19990
XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:7
Exact Mass:252.09977361
Heavy Atom Count:18
Complexity:265

Purity/Quality:

98%Min ^*data from raw suppliers

DIMETHYL-2-(4-METHOXYBENZYL)MALONATE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=C(C=C1)CC(C(=O)OC)C(=O)OC

Technology Process of Dimethyl 2-(4-methoxybenzyl)malonate

There total 8 articles about Dimethyl 2-(4-methoxybenzyl)malonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 7443-25-6
dimethyl 2-(4-methoxybenzylidene)malonate

: 15378-09-3
dimethyl 2-(4'-methoxybenzyl)malonate

Guidance literature:: With hydrogen; palladium on activated charcoal; In methanol;
DOI:10.1016/j.tet.2004.11.081

Reference yield: 97.0%

: 18424-76-5
sodiodimethylmalonate

: 105-13-5
4-Methoxybenzyl alcohol

: 15378-09-3
dimethyl 2-(4'-methoxybenzyl)malonate

Guidance literature:: 4-Methoxybenzyl alcohol; With trifluoromethylsulfonic anhydride; 1,1'-sulfinylbisbenzene; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; In toluene; at -78 ℃;

sodiodimethylmalonate; In tetrahydrofuran; toluene; at -78 - 20 ℃;
DOI:10.1246/cl.2004.8

Reference yield: 92.0%

: 105-13-5
4-Methoxybenzyl alcohol

: 108-59-8
malonic acid dimethyl ester

: 15378-09-3
dimethyl 2-(4'-methoxybenzyl)malonate

Guidance literature:: With 1,3-bis-(diphenylphosphino)propane; palladium diacetate; caesium carbonate; carbonic acid dimethyl ester; at 120 ℃; for 15h; Inert atmosphere;
DOI:10.1039/c6gc00163g