tetrakis(cyano-kappaC)platinate(2-)

Base Information

• Chemical Name: tetrakis(cyano-kappaC)platinate(2-)
• CAS No.: 15004-88-3
• Molecular Formula: C4N4 Pt
• Molecular Weight: 299.151
• Mol file: 15004-88-3.mol

Synonyms:[Pt(CN)4]2-;tetrakis(cyano-kappaC)platinate(2-)

Chemical Property of tetrakis(cyano-kappaC)platinate(2-)

Chemical Property:

• PSA: 95.16000
• LogP: 0.06462
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 298.977090
• Heavy Atom Count: 9
• Complexity: 76.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#N.[C-]#N.[C-]#N.[C-]#N.[Pt+2]

Technology Process of tetrakis(cyano-kappaC)platinate(2-)

There total 1 articles about tetrakis(cyano-kappaC)platinate(2-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-Pt(CN)4I2(2-) (20756-59-6,732183-96-9) → tetracyanoplatinate(II) (15004-88-3) + iodine (7553-56-2,12190-71-5,8031-47-8)

Guidance literature:

In perchloric acid; 0.50 M HClO4, 25°C; not isolated, reaction followed by stopped-flow UV/VIS spectroscopy; Kinetics;

DOI:10.1016/S0020-1693(00)91090-9

Reference yield:

tetracyanoplatinate(II) (15004-88-3) + (14)CN(1-) → cyanide(1-) (57-12-5)

Guidance literature:

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + tetrachloroplatinum(II) (13965-91-8) + tetracyanoplatinate(II) (15004-88-3) + chlorine (7782-50-5) → hexachloroplatinate(II) (16871-54-8)

Guidance literature:

With water; In hydrogenchloride; perchloric acid; treatment of cyanocomplex with Cl2, addn. of excess PtCl4(2-), standing at 50°C with protection from light (0.300-0.960 M HCl, I=1.00 M HClO4); not isolated, reaction followed by UV/VIS spectroscopy; Kinetics;

DOI:10.1016/S0020-1693(00)91070-3

upstream raw materials:

trans-Pt(CN)4I₂^(2-)

Downstream raw materials:

hexachloroplatinate(II)

cyanide^(1-)

Refernces