dimethylamidotitanium(IV) trichloride

Base Information

• Chemical Name: dimethylamidotitanium(IV) trichloride
• CAS No.: 16530-75-9
• Molecular Formula: C₂H₆Cl₃NTi
• Molecular Weight: 198.315
• Mol file: 16530-75-9.mol

Synonyms:dimethylamidotitanium(IV) trichloride

Chemical Property of dimethylamidotitanium(IV) trichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of dimethylamidotitanium(IV) trichloride

There total 1 articles about dimethylamidotitanium(IV) trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(N,N-dimethylamino)dimethylchlorosilane (18209-60-4) + titanium tetrachloride (7550-45-0) → dimethylamidotitanium(IV) trichloride (16530-75-9) + dimethylsilicon dichloride (75-78-5,30107-43-8)

Guidance literature:

In hexane; 24 h;

DOI:10.1039/DT9810001264

Reference yield: 100.0%

dimethylamidotitanium(IV) trichloride (16530-75-9) + (2,4,6-trimethylphenyl)-[6-(2,4,6-trimethylphenyl)pyridin-2-yl]-amine (896128-21-5) → [(N-(2,4,6-trimethylphenyl)-[6-(2,4,6-trimethylphenyl)pyridin-2-yl]amine)TiCl3(NHMe2)] (1279715-11-5)

Guidance literature:

In diethyl ether; (Ar) Ti complex and ligand in ether were stirred overnight at room temp.; solvent was removed in vacuo; elem. anal.;

DOI:10.1021/ic200318h

Reference yield: 98.0%

dimethylamidotitanium(IV) trichloride (16530-75-9) + (2,6-diisopropylphenyl)-[6-(2,6-dimethylphenyl)-pyridin-2-yl]amine (833453-24-0) → [(N-(2,6-diisopropylphenyl)-[6-(2,6-dimethylphenyl)pyridin-2-yl]amine)TiCl3(NHMe2)] (1279715-09-1)

Guidance literature:

In diethyl ether; (Ar) Ti complex and ligand in ether were stirred overnight; solvent was removed in vacuo; elem. anal.;

DOI:10.1021/ic200318h

upstream raw materials:

(N,N-dimethylamino)dimethylchlorosilane

titanium tetrachloride

Downstream raw materials:

tetrachlorobis(tetrahydrofuran)titanium(IV)

titanium tetrachloride

GeCl₃[N(CH₃)2]

chloro-(dimethylamino-dichlorotitanium)-2,6-diisopropylphenylamino-2',2',6',6'-tetramethylpiperidino-borane

Refernces