5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE VANADIUM(IV) OXIDE

Base Information

• Chemical Name: 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE VANADIUM(IV) OXIDE
• CAS No.: 14705-63-6
• Molecular Formula: C44H28 N4 O V
• Molecular Weight: 679.674
• Hs Code.: 29310099
• Mol file: 14705-63-6.mol

Synonyms:Porphine,tetraphenyl-, V complex (6CI); Vanadium, oxo[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-5-12)-; Vanadium, oxo[5,10,15,20-tetraphenylporphinato(2-)]- (8CI);Vanadium, oxo[a,b,g,d-tetraphenylporphinato(2-)]- (7CI); 21H,23H-Porphine,5,10,15,20-tetraphenyl-, vanadium complex; 21H,23H-Porphine, vanadium deriv.;(5,10,15,20-Tetraphenyl-21H,23H-porphine)vanadium(IV) oxide;5,10,15,20-tetraphenyl-21 H,23H-porphine vanadium(IV) oxide;Oxo(5,10,15,20-tetraphenylporphinato)vanadium;Oxo(tetraphenylporphyrinato)vanadium; Oxo[5,10,15,20-tetraphenylporphinato(2-)]vanadium;Oxovanadium(IV) tetraphenylporphyrin; Vanadyl tetraphenylporphine;Vanadyltetraphenylporphyrin

Chemical Property of 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE VANADIUM(IV) OXIDE

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 51.65000
• Density: g/cm³
• LogP: 6.31900
• Storage Temp.: -20°C
• Water Solubility.: Insoluble in water.

Purity/Quality:

98%,99%, ^*data from raw suppliers

VanadylMeso-Tetraphenylporphine(1-3%Chlorin) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Uses: It is used for research in catalysis. Thin films of VOTPP may be used in detecting methane gas.

Technology Process of 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE VANADIUM(IV) OXIDE

There total 11 articles about 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE VANADIUM(IV) OXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

vanadium(IV) oxide sulfate hydrate (12440-03-8,772292-34-9,121437-28-3,22534-68-5) + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → oxovanadium(IV) tetraphenylporphyrin (14705-63-6)

Guidance literature:

In N,N-dimethyl-formamide; for 16h; Reflux; Inert atmosphere;

DOI:10.1002/ejic.202100116

Reference yield: 90.0%

bis(acetylacetonate)oxidovanadium(IV) + 5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) → oxovanadium(IV) tetraphenylporphyrin (14705-63-6)

Guidance literature:

In quinoline; soln. of porphyrin in quinoline heated to reflux (in the dark, under N2), addn. of VO(acac)2, stirred (2 h), monitored by UV; evapn., extn. (CH2Cl2), filtration (short alumina column), slow evapn.,addn. of MeOH, crystn.;

DOI:10.1016/S0020-1693(00)81309-2

Reference yield: 70.0%

bis(acetylacetonate)oxovanadium (3153-26-2) + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → oxovanadium(IV) tetraphenylporphyrin (14705-63-6)

Guidance literature:

In phenol; at 180 ℃; for 9h;

DOI:10.1021/jacs.8b06733

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

bis(acetylacetonate)oxovanadium

vanadium(IV) oxide sulfate hydrate

5,15,10,20-tetraphenylporphyrin

Downstream raw materials:

tetraphenylporphyrinatovanadium(IV) dichloride

dibromo(5,10,15,20-tetraphenylporphyrinato)vanadium(IV)

tetraphenylporphyrinatovanadium(IV) chloride