Ethyl 5-(bromomethyl)thiophene-2-carboxylate

Base Information

Chemical Name:Ethyl 5-(bromomethyl)thiophene-2-carboxylate
CAS No.:14282-72-5
Molecular Formula:C₈H₉BrO₂S
Molecular Weight:249.128
Hs Code.:2934999090
DSSTox Substance ID:DTXSID90570989
Wikidata:Q82458565
Mol file:14282-72-5.mol

Synonyms:14282-72-5;Ethyl 5-(bromomethyl)thiophene-2-carboxylate;2-Bromomethylthiophene-5-carboxylic acid ethyl ester;Ethyl5-(bromomethyl)thiophene-2-carboxylate;SCHEMBL6848383;DTXSID90570989;MB07586

Suppliers and Price of Ethyl 5-(bromomethyl)thiophene-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Ethyl5-(bromomethyl)thiophene-2-carboxylate 95+%
1g
$ 377.00

Chemenu
ethyl5-(bromomethyl)thiophene-2-carboxylate 95%
1g
$ 356.00

Arctom
Ethyl5-(bromomethyl)thiophene-2-carboxylate
1g
$ 353.00

American Custom Chemicals Corporation
2-BROMOMETHYLTHIOPHENE-5-CARBOXYLIC ACID ETHYL ESTER 95.00%
5MG
$ 501.19

Alichem
Ethyl5-(bromomethyl)thiophene-2-carboxylate
1g
$ 429.24

Total 5 raw suppliers

Chemical Property of Ethyl 5-(bromomethyl)thiophene-2-carboxylate

Chemical Property:

PSA：54.54000
LogP:2.81970
Storage Temp.:2-8°C
XLogP3:2.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:247.95066
Heavy Atom Count:12
Complexity:163

Purity/Quality:

97% ^*data from raw suppliers

Ethyl5-(bromomethyl)thiophene-2-carboxylate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1=CC=C(S1)CBr

Technology Process of Ethyl 5-(bromomethyl)thiophene-2-carboxylate

There total 3 articles about Ethyl 5-(bromomethyl)thiophene-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 5751-81-5
5-methyl-thiophene-2-carboxylic acid ethyl ester

: 14282-72-5
ethyl 5-(bromomethyl)thiophene-2-carboxylate

Guidance literature:: With N-Bromosuccinimide; dibenzoyl peroxide; In tetrachloromethane; for 2h; Reflux;
DOI:10.1016/j.ejmech.2018.03.005

Reference yield:

: 128-08-5
N-Bromosuccinimide

: 5751-81-5
5-methyl-thiophene-2-carboxylic acid ethyl ester

: 14282-72-5
ethyl 5-(bromomethyl)thiophene-2-carboxylate

Guidance literature:: With dibenzoyl peroxide; SiO₂; In water; ethyl acetate; benzene;

Reference yield:

: 1918-79-2
2-methylthiophene-5-carboxylic acid

: 14282-72-5
ethyl 5-(bromomethyl)thiophene-2-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / N,N-dimethyl-formamide / 20 °C

2: dibenzoyl peroxide; N-Bromosuccinimide / tetrachloromethane / 2 h / Reflux

With N-Bromosuccinimide; potassium carbonate; dibenzoyl peroxide; In tetrachloromethane; N,N-dimethyl-formamide;