9-m-carboranylbenzenesulfinate

Base Information

Chemical Name:9-m-carboranylbenzenesulfinate
CAS No.:83645-32-3
Molecular Formula:C₈H₁₆B₁₀O₂S
Molecular Weight:284.39
Hs Code.:

Synonyms:9-m-carboranylbenzenesulfinate

Suppliers and Price of 9-m-carboranylbenzenesulfinate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 9-m-carboranylbenzenesulfinate

Chemical Property:

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Technology Process of 9-m-carboranylbenzenesulfinate

There total 1 articles about 9-m-carboranylbenzenesulfinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 84643-47-0
phenyl(m-carboran-9-yl)bromonium tetrafluoroborate

: 873-55-2
sodium benzenesulfonate

: 17819-81-7
9-bromo(1,7-dicarba-closo-dodecaborane⁽¹²⁾)

: 83645-32-3
9-m-carboranylbenzenesulfinate

Guidance literature:: In dichloromethane; water; mixt. of C6H5SO2Na and phenyl-(9-m-carboranyl)bromonium borofluoride inCH2Cl2 and water stirred 7h at 20 °C.; organic layer filtered through Al2O3, CH2Cl2 removed in vac., pptn. with pentane, identification. by mp.;
DOI:10.1007/BF00953942

Reference yield: 43.0%

: 83645-32-3
9-m-carboranylbenzenesulfinate

: 7803-57-8,79785-97-0
hydrazine hydrate

: 54360-42-8
9-hydroxy-1,7-dicarba-closo-dodecaborane

: 882-33-7
diphenyldisulfane

Guidance literature:: In neat (no solvent); byproducts: N2; heating a mixt. of carboranyl compd. and hydrazine hydrate on a steam bath for 2.5 h, liberation of N2; leaving mixt. overnight, dissolution of reaction mixt. in benzene, extn. with aq. NaOH, acidification with aq. H2SO4 yields carboranyl compd., evapn. of benzene layer in vacuum, hexane extn. of residue gives (PhS)2;