9-hydroxy-1,7-dicarba-closo-dodecaborane

Base Information

Chemical Name:9-hydroxy-1,7-dicarba-closo-dodecaborane
CAS No.:54360-42-8
Molecular Formula:C₂H₁₂B₁₀O
Molecular Weight:160.227
Hs Code.:

Synonyms:9-hydroxy-1,7-dicarba-closo-dodecaborane

Suppliers and Price of 9-hydroxy-1,7-dicarba-closo-dodecaborane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 9-hydroxy-1,7-dicarba-closo-dodecaborane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 9-hydroxy-1,7-dicarba-closo-dodecaborane

There total 10 articles about 9-hydroxy-1,7-dicarba-closo-dodecaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 84643-47-0
phenyl(m-carboran-9-yl)bromonium tetrafluoroborate

: 108-86-1,52753-63-6
bromobenzene

: 17819-81-7
9-bromo(1,7-dicarba-closo-dodecaborane⁽¹²⁾)

: 54360-42-8
9-hydroxy-1,7-dicarba-closo-dodecaborane

: 98-95-3,26969-40-4
nitrobenzene

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

Guidance literature:: With sodium nitrite; In dichloromethane; water; vigorously stirred under reflux for 2.5 h; GLC, chromatographed (silica, 1. hexane, 2. ether);

Reference yield: 87.0%

: 99506-45-3
4-methoxyphenyl(m-carboran-9-yl)iodonium tetrafluoroborate

: 17157-02-7
9-iodo-m-carborane

: 54360-42-8
9-hydroxy-1,7-dicarba-closo-dodecaborane

: 114992-96-0
9-nitro-m-carbaborane

: 696-62-8
para-iodoanisole

: 100-66-3
methoxybenzene

Guidance literature:: With sodium nitrite; In dichloromethane; water; mixt. of NaNO2 and the boron contg. salt in a two phase system stirred vigorously at 40°C, 3h (accompanied by evolution of nitrogen oxides), further product: C6H5NO2 (traces); organic layer sepd. from aq. layer, evapn. of CH2Cl2 in vac., residue sepd. by chromy. (silica gel, hexane (9-iodo-m-carbaborane); benzene-hexane 1:1 (9-nitro-m-carbaborane); ether (9-hydroxy-m-carbaborane);

Reference yield: 79.0%

: 81353-33-5
phenyl(m-carboran-9-yl)iodonium tetrafluoroborate

: 591-50-4
iodobenzene

: 17157-02-7
9-iodo-m-carborane

: 54360-42-8
9-hydroxy-1,7-dicarba-closo-dodecaborane

: 114992-96-0
9-nitro-m-carbaborane

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

Guidance literature:: With sodium nitrite; In dichloromethane; water; mixt. of NaNO2 and the boron contg. salt in a two phase system stirred vigorously at 40°C, 3h (accompanied by evolution of nitrogen oxides), further product: C6H5NO2 (4%); organic layer sepd. from aq. layer, evapn. of CH2Cl2 in vac., residue sepd. by chromy. (silica gel, hexane (9-iodo-m-carbaborane); benzene-hexane 1:1 (9-nitro-m-carbaborane); ether (9-hydroxy-m-carbaborane);