2,6-diallylbenzoic acid

Base Information

• Chemical Name: 2,6-diallylbenzoic acid
• CAS No.: 1344667-75-9
• Molecular Formula: C₁₃H₁₄O₂
• Molecular Weight: 202.253
• Mol file: 1344667-75-9.mol

Synonyms:2,6-diallylbenzoic acid

Chemical Property of 2,6-diallylbenzoic acid

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 2,6-diallylbenzoic acid

There total 2 articles about 2,6-diallylbenzoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

N,N-diethylallylamine (5666-17-1) + benzoic acid (65-85-0,8013-63-6) → 2-allylbenzoic acid (61436-73-5) + 2,6-diallylbenzoic acid (1344667-75-9)

Guidance literature:

With [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; trifluoroacetic acid; at 60 ℃; for 24h; regiospecific reaction; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.orglett.8b01762

Reference yield:

Allyl acetate (591-87-7) + vinyl benzoate (583-04-0) → 2-allylbenzoic acid (61436-73-5) + 2,6-diallylbenzoic acid (1344667-75-9)

Guidance literature:

Allyl acetate; vinyl benzoate; With decacarbonyldirhenium⁽⁰⁾; In 1,2-dichloro-ethane; at 135 ℃; for 24h; Inert atmosphere;

With 3-Methyl-2,4-pentanedione; In 1,2-dichloro-ethane; at 115 ℃; for 6h; Inert atmosphere;

DOI:10.1039/c1cc12359a

upstream raw materials:

Allyl acetate

vinyl benzoate

N,N-diethylallylamine

benzoic acid