Di-(pentafluorophenyl)phosphinbromid

Base Information

• Chemical Name: Di-(pentafluorophenyl)phosphinbromid
• CAS No.: 13648-79-8
• Molecular Formula: C12Br F10 P
• Molecular Weight: 444.994
• Hs Code.: 2903999090
• Mol file: 13648-79-8.mol

Synonyms:Phosphinousbromide, bis(pentafluorophenyl)- (8CI,9CI); Bis(pentafluorophenyl)phosphinousbromide; Bromobis(pentafluorophenyl)phosphine

Chemical Property of Di-(pentafluorophenyl)phosphinbromid

Chemical Property:

• Vapor Pressure: 0.00118mmHg at 25°C
• Boiling Point: 309.3°C at 760 mmHg
• Flash Point: 140.8°C
• PSA: 13.59000
• LogP: 4.82020

Purity/Quality:

98%min ^*data from raw suppliers

BIS-(PENTAFLUOROPHENYL)BROMOPHOSPHINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Di-(pentafluorophenyl)phosphinbromid

There total 4 articles about Di-(pentafluorophenyl)phosphinbromid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

bromopentafluorobenzene (344-04-7) → bis(pentafluorophenyl)bromophosphine (13648-79-8)

Guidance literature:

bromopentafluorobenzene; With magnesium; In diethyl ether; Inert atmosphere;

With phosphorus trichloride; In diethyl ether; at -50 - 20 ℃; for 74h; Inert atmosphere;

DOI:10.1007/s11172-014-0741-1

Reference yield:

2,3,4,5,6-pentafluorophenylmagnesium bromide (879-05-0) + phosphorus trichloride (7719-12-2,52843-90-0) → pentafluorophenyl-phosphonous acid dibromide (13379-67-4) + bis(pentafluorophenyl)bromophosphine (13648-79-8)

Guidance literature:

Reference yield:

2,3,4,5,6-pentafluorophenylmagnesium bromide (879-05-0) → bis(pentafluorophenyl)bromophosphine (13648-79-8)

Guidance literature:

With phosphorus tribromide;

DOI:10.1039/DT9900002593

upstream raw materials:

bromopentafluorobenzene

2,3,4,5,6-pentafluorophenylmagnesium bromide

phosphorus trichloride

Downstream raw materials:

R,R-P(C₆F₅)2OC₅H₈OP(C₆H₅)2

C₁₂BrF₁₀IP^(1-)*C₁₂H₂₈N⁽¹⁺⁾

C₁₂Br₂F₁₀P^(1-)*C₁₂H₂₈N⁽¹⁺⁾

Bis-pentafluorphenyl-ethyl-phosphin