Dibromo(pentafluorophenyl)phosphine

Base Information

• Chemical Name: Dibromo(pentafluorophenyl)phosphine
• CAS No.: 13379-67-4
• Molecular Formula: C6Br2F5P
• Molecular Weight: 357.84
• Hs Code.: 2903999090
• DSSTox Substance ID: DTXSID90345896
• Nikkaji Number: J46.729D
• Wikidata: Q82118688
• Mol file: 13379-67-4.mol

Synonyms:Dibromo(pentafluorophenyl)phosphine;13379-67-4;dibromo-(2,3,4,5,6-pentafluorophenyl)phosphane;Phosphonous dibromide, (pentafluorophenyl)-;Pentafluorophenyldibromophosphine;SCHEMBL1041997;DTXSID90345896;2,3,4,5,6-Pentafluorophenylphosphonous dibromide #

Chemical Property of Dibromo(pentafluorophenyl)phosphine

Chemical Property:

• PSA: 13.59000
• LogP: 4.10910
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 357.80040
• Heavy Atom Count: 14
• Complexity: 191

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1(=C(C(=C(C(=C1F)F)P(Br)Br)F)F)F

Technology Process of Dibromo(pentafluorophenyl)phosphine

There total 8 articles about Dibromo(pentafluorophenyl)phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3,4,5,6-pentafluorophenylmagnesium bromide (879-05-0) + phosphorus tribromide (7789-60-8) → pentafluorophenyl-phosphonous acid dibromide (13379-67-4)

Guidance literature:

equimolar amts.;

DOI:10.1021/ja00971a060

Reference yield:

bromopentafluorobenzene (344-04-7) → pentafluorophenyl-phosphonous acid dibromide (13379-67-4)

Guidance literature:

With phosphorus tribromide; magnesium; Multistep reaction;

DOI:10.1039/DT9900000551

Reference yield:

pentafluorophenyl dichlorophosphine (5032-91-7) → pentafluorophenyl-phosphonous acid dibromide (13379-67-4)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether

In diethyl ether;

upstream raw materials:

bromopentafluorobenzene

Tetrakis(pentafluorphenyl)-cyclotetraphosphan

bromine

hydrogen bromide

Downstream raw materials:

C₁₂H₂₈N⁽¹⁺⁾*C₆Br₂F₅IP^(1-)

C₁₂H₂₈N⁽¹⁺⁾*C₆Br₃F₅P^(1-)

C₂₄H₅₂N⁽¹⁺⁾*C₆Br₃F₅P^(1-)

pentafluorophenylphosphorus cyanide