2-(((3aR,4R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[3,4-d]-[1,3]dioxol-4-yl)methoxy)ethyl 4-methylbenzenesulfonate

Base Information

Chemical Name:2-(((3aR,4R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[3,4-d]-[1,3]dioxol-4-yl)methoxy)ethyl 4-methylbenzenesulfonate
CAS No.:1352447-38-1
Molecular Formula:C₂₅H₃₂O₉S
Molecular Weight:508.59
Hs Code.:

Synonyms:2-(((3aR,4R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[3,4-d]-[1,3]dioxol-4-yl)methoxy)ethyl 4-methylbenzenesulfonate

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Chemical Property of 2-(((3aR,4R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[3,4-d]-[1,3]dioxol-4-yl)methoxy)ethyl 4-methylbenzenesulfonate

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Technology Process of 2-(((3aR,4R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[3,4-d]-[1,3]dioxol-4-yl)methoxy)ethyl 4-methylbenzenesulfonate

There total 7 articles about 2-(((3aR,4R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[3,4-d]-[1,3]dioxol-4-yl)methoxy)ethyl 4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.3%

: 1352447-37-0
2-(((3aR,4R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[3,4-d]-[1,3]dioxol-4-yl)methoxy)ethanol

: 98-59-9
p-toluenesulfonyl chloride

: 1352447-38-1
2-(((3aR,4R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[3,4-d]-[1,3]dioxol-4-yl)methoxy)ethyl 4-methylbenzenesulfonate

Guidance literature:: With 1,4-diaza-bicyclo[2.2.2]octane; triethylamine; In dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1016/j.tet.2011.10.063

Reference yield:

: C₁₉H₂₈O₈

: 1352447-38-1
2-(((3aR,4R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[3,4-d]-[1,3]dioxol-4-yl)methoxy)ethyl 4-methylbenzenesulfonate

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium periodate / dichloromethane; water / 3 h / 20 °C

2.1: sodium tetrahydroborate / methanol / 0.5 h / 0 °C

2.2: Saturated solution

3.1: 1,4-diaza-bicyclo[2.2.2]octane; triethylamine / dichloromethane / 0.5 h / 20 °C

With 1,4-diaza-bicyclo[2.2.2]octane; sodium tetrahydroborate; sodium periodate; triethylamine; In methanol; dichloromethane; water;
DOI:10.1016/j.tet.2011.10.063

Reference yield:

: C₁₈H₂₄O₇

: 1352447-38-1
2-(((3aR,4R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyltetrahydrofuro[3,4-d]-[1,3]dioxol-4-yl)methoxy)ethyl 4-methylbenzenesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium tetrahydroborate / methanol / 0.5 h / 0 °C

1.2: Saturated solution

2.1: 1,4-diaza-bicyclo[2.2.2]octane; triethylamine / dichloromethane / 0.5 h / 20 °C

With 1,4-diaza-bicyclo[2.2.2]octane; sodium tetrahydroborate; triethylamine; In methanol; dichloromethane;
DOI:10.1016/j.tet.2011.10.063