(2'R,4'S)-<5'-<(tert-butyldimethylsilyl)oxy>-2',4'-dimethyl-pentyloxymethyl>benzene

Base Information

Chemical Name:(2'R,4'S)-<5'-<(tert-butyldimethylsilyl)oxy>-2',4'-dimethyl-pentyloxymethyl>benzene
CAS No.:157733-61-4
Molecular Formula:C₂₀H₃₆O₂Si
Molecular Weight:336.59
Hs Code.:

Synonyms:(2'R,4'S)-<5'-<(tert-butyldimethylsilyl)oxy>-2',4'-dimethyl-pentyloxymethyl>benzene

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Chemical Property of (2'R,4'S)-<5'-<(tert-butyldimethylsilyl)oxy>-2',4'-dimethyl-pentyloxymethyl>benzene

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Technology Process of (2'R,4'S)-<5'-<(tert-butyldimethylsilyl)oxy>-2',4'-dimethyl-pentyloxymethyl>benzene

There total 6 articles about (2'R,4'S)-<5'-<(tert-butyldimethylsilyl)oxy>-2',4'-dimethyl-pentyloxymethyl>benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 157810-31-6
(2S,4R)-5-(benzyloxy)-2,4-dimethylpentan-1-ol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 157733-61-4
(2'R,4'S)-<5'-<(tert-butyldimethylsilyl)oxy>-2',4'-dimethyl-pentyloxymethyl>benzene

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 18h; Ambient temperature;

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 157810-31-6
(2S,4R)-5-(benzyloxy)-2,4-dimethylpentan-1-ol

: 157733-61-4
(2'R,4'S)-<5'-<(tert-butyldimethylsilyl)oxy>-2',4'-dimethyl-pentyloxymethyl>benzene

Guidance literature:: With lutidine; In dichloromethane; at -20 ℃;
DOI:10.1002/hlca.19910740846

Reference yield:

: 81927-55-1
O-benzyl 2,2,2-trichloroacetimidate

: 157733-61-4
(2'R,4'S)-<5'-<(tert-butyldimethylsilyl)oxy>-2',4'-dimethyl-pentyloxymethyl>benzene

Guidance literature:: Multi-step reaction with 3 steps

1: 59 percent / trifluoromethanesulfonic acid / cyclohexane; CH₂Cl₂ / 4 h / Ambient temperature

2: 99 percent / 80percent LiAlH₄ / diethyl ether / 1 h / Ambient temperature

3: 88 percent / imidazole / dimethylformamide / 18 h / Ambient temperature

With 1H-imidazole; lithium aluminium tetrahydride; trifluorormethanesulfonic acid; In diethyl ether; dichloromethane; cyclohexane; N,N-dimethyl-formamide;