[Ph₃PCH₂Ph][PtCl₃(EtCN)]

Base Information

• Chemical Name: [Ph₃PCH₂Ph][PtCl₃(EtCN)]
• CAS No.: 330476-14-7
• Molecular Formula: C₃H₅Cl₃NPt*C₂₅H₂₂P
• Molecular Weight: 709.942
• Mol file: 330476-14-7.mol

Synonyms:[Ph₃PCH₂Ph][PtCl₃(EtCN)]

Chemical Property of [Ph₃PCH₂Ph][PtCl₃(EtCN)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of [Ph₃PCH₂Ph][PtCl₃(EtCN)]

There total 1 articles about [Ph₃PCH₂Ph][PtCl₃(EtCN)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

[PtCl2(propionitrile)2] (28005-97-2,146143-88-6,15617-14-8) + benzyltriphenylphosphonium chloride (1100-88-5) → [Ph3PCH2Ph][PtCl3(EtCN)] (330476-14-7)

Guidance literature:

In chloroform; byproducts: EtCN; stirring of mixt. of cis- and trans-PtCl2(EtCN)2 in CHCl3; heating at 50°C, addn. of (Ph3PCH2Ph)Cl; heating to 50°C for 1 h; holding at 20-25°C for 1 d; crystn., filtration, washing with EtOH, drying in air at room temp.; evapn. of filtrate to dryness, washing of residue thoroughly with EtOH; recrystn from acetone-toluene mixt.; elem. anal.;

DOI:10.1039/b006168i

Reference yield: 62.0%

5,5-Dimethyl-1-pyrroline N-oxide (3317-61-1) + diethyl ether (60-29-7,927820-24-4) + [Ph3PCH2Ph][PtCl3(EtCN)] (330476-14-7) → (C6H5)3PCH2C6H5(1+)*PtCl3(NCC2H5ONC(CH3)2C2H4CH)(1-)*0.5(C2H5)2O=[(C6H5)3PC7H7][PtCl3(NCC2H5ONC(CH3)2C2H4CH)]*0.5C4H10O

Guidance literature:

In dichloromethane; other Radiation; soln. of Pt complex and ligand in CH2Cl2/EtCN was placed in focused microwave at 30°C for 3 h; cooled; solvent removed (vac.); chromd. (SiO2, CH2Cl2); solvent evapd.; dried (vac.);

Reference yield:

N,N-dimethylhydroxylamine (5725-96-2) + [Ph3PCH2Ph][PtCl3(EtCN)] (330476-14-7) → [Ph3PCH2Ph][PtCl3(NH=C(Et)ONMe2)] (851474-54-9)

Guidance literature:

In chloroform; Pt complex suspended in CHCl3 at 20-25°C, (CH3)2NOH added, stirred for 12 h at room temp.; evapd. under N2, washed (Et2O); elem. anal.;

DOI:10.1021/ic048388c

upstream raw materials:

[PtCl₂(propionitrile)₂]

benzyltriphenylphosphonium chloride

Downstream raw materials:

[Ph₃PCH₂Ph][PtCl₅(EtCN)]

[Ph₃PCH₂Ph][PtCl₃(NH=C(Et)ON(CH₂C₆H₄Cl-p)2)]

[Ph₃PCH₂Ph][PtCl₃(NH=C(Et)ONMe₂)]

[Ph₃PCH₂Ph][PtCl₃(NH=C(Et)ONEt₂)]

Refernces