[1-(4-methoxyphenyl)-prop-2-yn-1-ol]dicobalthexacarbonyl

Base Information

Chemical Name:[1-(4-methoxyphenyl)-prop-2-yn-1-ol]dicobalthexacarbonyl
CAS No.:610802-73-8
Molecular Formula:C₁₆H₁₀Co₂O₈
Molecular Weight:448.237
Hs Code.:

Synonyms:[1-(4-methoxyphenyl)-prop-2-yn-1-ol]dicobalthexacarbonyl

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [1-(4-methoxyphenyl)-prop-2-yn-1-ol]dicobalthexacarbonyl

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Technology Process of [1-(4-methoxyphenyl)-prop-2-yn-1-ol]dicobalthexacarbonyl

There total 1 articles about [1-(4-methoxyphenyl)-prop-2-yn-1-ol]dicobalthexacarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.1%

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 19115-30-1
1-(4-methoxyphenyl)-2-propyn-1-ol

: 610802-73-8
[1-(4-methoxyphenyl)-prop-2-yn-1-ol]dicobalthexacarbonyl

Guidance literature:: In diethyl ether; under N2; soln. of alcohol in dry ether added dropwise to soln. of Co2(CO)8 in ether at 20°C, stirred for 3 h; evapd. under reduced pressure, column chromy. (Florisil, petroleum etherand petroleum ether/ether (5/1) and (2/1)); elem. anal.;
DOI:10.1016/S0022-328X(03)00539-4

Reference yield: 77.1%

: 67-56-1
methanol

: 610802-73-8
[1-(4-methoxyphenyl)-prop-2-yn-1-ol]dicobalthexacarbonyl

: 1144513-87-0
(μ-η2-3-methoxy-3-(4'-methoxyphenyl)-1-propyne)dicobalt hexacarbonyl

Guidance literature:: With HBF₄*(CH₃)2O; In methanol; diethyl ether; (N2); Schlenk technique; soln. of acid added dropwise over 5 min to soln. of Co complex in ether at -20°C; stirred for 1 h; ethereal layer removed; washed (ether, -20°C); ether added at -20°C; MeOH added; stirred (20°C, 0.5 h; dild. with H2O; org. layer washed (H2O); dried (Na2SO4); evapd. (vac.); filtered through Florisil; elem. anal.;
DOI:10.1021/om900448j

Reference yield: 69.0%

: 610802-73-8
[1-(4-methoxyphenyl)-prop-2-yn-1-ol]dicobalthexacarbonyl

: 67969-83-9
tetrafluoroboric acid dimethyl ether complex

: 65979-04-6
(3-(4-methoxyphenyl)-1-propyne)dicobalthexacarbonyl

: meso-μ-η2-[3,4-di(4'-methoxyphenyl)-1,5-hexadiyne]bis(dicobalthexacarbonyl)

: d,l-μ-η2-[3,4-di(4'-methoxyphenyl)-1,5-hexadiyne]bis(dicobalthexacarbonyl)

Guidance literature:: In diethyl ether; under N2; HBF4*Me2O added to soln. of Co complex in Et2O at -20°C, stirred at -20°C for 1 h, the ether layer removed, residue washed with ether at -20°C, ether evapd., CH2Cl2 and THF added, stirred at 20°C; TLC (silica gel, petroleum ether/ether (7/1));
DOI:10.1016/S0022-328X(03)00539-4