[Ru(η5-indenyl)(C.ident.CC6H4Me-p)l(κ1(P)-allyldiphenylphosphine))(PPh3)]

Base Information

Chemical Name:[Ru(η5-indenyl)(C.ident.CC6H4Me-p)l(κ1(P)-allyldiphenylphosphine))(PPh3)]
CAS No.:503584-77-8
Molecular Formula:C₅₁H₄₄P₂Ru
Molecular Weight:819.928
Hs Code.:

Synonyms:[Ru(η5-indenyl)(C.ident.CC6H4Me-p)l(κ1(P)-allyldiphenylphosphine))(PPh3)]

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Chemical Property of [Ru(η5-indenyl)(C.ident.CC6H4Me-p)l(κ1(P)-allyldiphenylphosphine))(PPh3)]

Chemical Property:

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Technology Process of [Ru(η5-indenyl)(C.ident.CC6H4Me-p)l(κ1(P)-allyldiphenylphosphine))(PPh3)]

There total 1 articles about [Ru(η5-indenyl)(C.ident.CC6H4Me-p)l(κ1(P)-allyldiphenylphosphine))(PPh3)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 503584-78-9
[Ru(η5-indenyl)Cl(κ1(P)-allyldiphenylphosphine))(PPh3)]

: 503584-77-8
[Ru(η5-indenyl)(C.ident.CC6H4Me-p)l(κ1(P)-allyldiphenylphosphine))(PPh3)]

Guidance literature:: With KO(C(CH₃)3); In dichloromethane; treatment of Ru(C9H7)Cl(PPh2C3H5)(PPh3) with alkyne and KO(t-Bu) in CH2Cl2;
DOI:10.1021/ja027209s

Reference yield: 95.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 503584-77-8
[Ru(η5-indenyl)(C.ident.CC6H4Me-p)l(κ1(P)-allyldiphenylphosphine))(PPh3)]

: [Ru(η5-indenyl)(=C=C(C6H4Me-p)H)l(κ1(P)-allyldiphenylphosphine))(PPh3)][BF4]

Guidance literature:: In diethyl ether; (N2); dropwise addn. of a soln. of acid in Et2O to a soln. of ruthenium complex in Et2O at room temp.; filtration, washing with Et2O, drying in vac.; elem. anal.;
DOI:10.1021/om040068d

Reference yield: 90.0%

: 503584-77-8
[Ru(η5-indenyl)(C.ident.CC6H4Me-p)l(κ1(P)-allyldiphenylphosphine))(PPh3)]

: 333-27-7
methyl trifluoromethanesulfonate

: [Ru(η5-indenyl)(=C=C(C6H4Me-p)Me)l(κ1(P)-allyldiphenylphosphine))(PPh3)][OSO2CF3]

Guidance literature:: In diethyl ether; (N2); dropwise addn. of a soln. of methyl triflate to a soln. of ruthenium complex in Et2O at room temp.; decantation, recrystn. (CH2Cl2/Et2O), drying in vac.; elem. anal.;
DOI:10.1021/om040068d