1-ferrocenyl-1-methoxy-1-phenylbut-3-yne

Base Information

Chemical Name:1-ferrocenyl-1-methoxy-1-phenylbut-3-yne
CAS No.:672958-85-9
Molecular Formula:C₂₁H₂₀FeO
Molecular Weight:344.236
Hs Code.:

Synonyms:1-ferrocenyl-1-methoxy-1-phenylbut-3-yne

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Chemical Property of 1-ferrocenyl-1-methoxy-1-phenylbut-3-yne

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Technology Process of 1-ferrocenyl-1-methoxy-1-phenylbut-3-yne

There total 1 articles about 1-ferrocenyl-1-methoxy-1-phenylbut-3-yne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 672958-84-8
1-ferrocenyl-1-phenylbut-3-ynol

: 74-88-4
methyl iodide

: 672958-85-9
1-ferrocenyl-1-methoxy-1-phenylbut-3-yne

Guidance literature:: With n-butyllithium; In tetrahydrofuran; pentane; a soln. of BuLi in pentane was added at -70°C under Ar to a THF soln. of butynol, the stirred mixt. was allowed to warm to -40°C, MeI was added, the mixt. was stirred overnight at room temp.; water was added, volatiles removed in vacuo, residue was dissolved in ether, soln. washed with water, dried over Na2SO4, evapd., residue was crystd. from hexane; elem. anal.;

Reference yield: 78.5%

: 1272-44-2
benzoylferrocene

: 672958-85-9
1-ferrocenyl-1-methoxy-1-phenylbut-3-yne

: 672958-86-0
1,5-diferrocenyl-5-methoxy-1,5-diphenylpent-2-ynol

Guidance literature:: With n-butyllithium; In tetrahydrofuran; pentane; a soln. of n-BuLi in pentane was added at -60°C under Ar to a THFsoln. of the butyne, the stirred was allowed to warm to room temp., FcC OPh was added, the mixt. was stirred for overnight; water was added, volatiles were removed in vacuo, the residue was dissolved in ether, soln. washed with aq. NaHCO3 and water, dried over Na2SO4,evapd., residue was chromd. on basic alumina (eluent 1:1 hexane-ether); elem. anal.;

Reference yield: 28.6%

: 672958-85-9
1-ferrocenyl-1-methoxy-1-phenylbut-3-yne

: 672959-02-3
3-ferrocenyl-1-iodo-3-methoxy-3-phenylpropyne

: 672959-05-6
1,6-diferrocenyl-1,6-dimethoxy-1,6-diphenylhexa-2,4-diyne

: 672959-03-4
1,7-diferrocenyl-1,7-dimethoxy-1,7-diphenylhepta-2,4-diyne

Guidance literature:: With pyridine; copper(I) bromide dimethylsulfide complex; methyllithium; In tetrahydrofuran; pyridine; diethyl ether; MeLi in Et2O was added under Ar at -60°C to a THF soln. of Fc(Ph)(OH)CCH2CCH, warmed to room temp., cooled to -60°C, CuBr*Me2S wasadded, stirred mixt. was warmed to room temp., concd. in vacuo, Py and iodide added, refluxed for 1 h; volatiles were removed in vacuo, residue was dissolved in CH2Cl2, soln. filtd., washed with water, dried with Na2SO4, evapd., residue was chromd. on basic alumina (eluent 5:1 hexane-ether); elem. anals.;