tert-butyl(((S,E)-6-((4S,5S)-5-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-3-methylhex-5-en-1-yl)oxy)diphenylsilane

Base Information

Chemical Name:tert-butyl(((S,E)-6-((4S,5S)-5-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-3-methylhex-5-en-1-yl)oxy)diphenylsilane
CAS No.:1313511-79-3
Molecular Formula:C₃₇H₅₀O₅Si
Molecular Weight:602.886
Hs Code.:

Synonyms:tert-butyl(((S,E)-6-((4S,5S)-5-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-3-methylhex-5-en-1-yl)oxy)diphenylsilane

Suppliers and Price of tert-butyl(((S,E)-6-((4S,5S)-5-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-3-methylhex-5-en-1-yl)oxy)diphenylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tert-butyl(((S,E)-6-((4S,5S)-5-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-3-methylhex-5-en-1-yl)oxy)diphenylsilane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tert-butyl(((S,E)-6-((4S,5S)-5-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-3-methylhex-5-en-1-yl)oxy)diphenylsilane

There total 12 articles about tert-butyl(((S,E)-6-((4S,5S)-5-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-3-methylhex-5-en-1-yl)oxy)diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 1313511-71-5
(R)-5-((5-((tert-butyldiphenylsilyl)oxy)-3-methylpentyl)sulfonyl)-1-phenyl-1H-tetrazole

: 132352-48-8
4-p-methoxybenzyl-2,3-O-isopropylidene-L-threose

: 1313511-79-3
tert-butyl(((S,E)-6-((4S,5S)-5-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-3-methylhex-5-en-1-yl)oxy)diphenylsilane

Guidance literature:: (R)-5-((5-((tert-butyldiphenylsilyl)oxy)-3-methylpentyl)sulfonyl)-1-phenyl-1H-tetrazole; With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃;

4-p-methoxybenzyl-2,3-O-isopropylidene-L-threose; In tetrahydrofuran; at -78 ℃; for 6.25h;
DOI:10.1039/c0ob01253j

Reference yield:

: 1313511-71-5
(R)-5-((5-((tert-butyldiphenylsilyl)oxy)-3-methylpentyl)sulfonyl)-1-phenyl-1H-tetrazole

: 132352-48-8
4-p-methoxybenzyl-2,3-O-isopropylidene-L-threose

: tert-butyl(((S,Z)-6-((4S,5S)-5-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-3-methylhex-5-en-1-yl)oxy)diphenylsilane

: 1313511-79-3
tert-butyl(((S,E)-6-((4S,5S)-5-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-3-methylhex-5-en-1-yl)oxy)diphenylsilane

Guidance literature:: With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; lithium hexamethyldisilazane; In N,N-dimethyl-formamide; at -78 - 20 ℃; optical yield given as %de;
DOI:10.1039/c0ob01253j

Reference yield:

: 1046471-35-5
(S)-5-(tert-butyldiphenylsilyloxy)-3-methylpentan-1-ol

: 1313511-79-3
tert-butyl(((S,E)-6-((4S,5S)-5-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-3-methylhex-5-en-1-yl)oxy)diphenylsilane

Guidance literature:: Multi-step reaction with 3 steps

1.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 0 - 20 °C

2.1: ammonium molybdate(VI) tetrahydrate; dihydrogen peroxide / ethanol; water / 0 °C

3.1: lithium hexamethyldisilazane / tetrahydrofuran / -78 °C

3.2: 6.25 h / -78 °C

With ammonium molybdate(VI) tetrahydrate; di-isopropyl azodicarboxylate; dihydrogen peroxide; triphenylphosphine; lithium hexamethyldisilazane; In tetrahydrofuran; ethanol; water; 1.1: Mitsunobu reaction / 3.1: Julia-Kocienski olefination / 3.2: Julia-Kocienski olefination;
DOI:10.1039/c0ob01253j