Ag⁽¹⁺⁾*S₂C(CH₃C₆H₄)NCHN(C₆H₄CH₃)^(1-)=[Ag(S₂C(CH₃C₆H₄)NCHNC₆H₄CH₃)]

Base Information

• Chemical Name: Ag⁽¹⁺⁾*S₂C(CH₃C₆H₄)NCHN(C₆H₄CH₃)^(1-)=[Ag(S₂C(CH₃C₆H₄)NCHNC₆H₄CH₃)]
• CAS No.: 116722-41-9
• Molecular Formula: Ag*C₁₆H₁₅N₂S₂
• Molecular Weight: 407.309
• Mol file: 116722-41-9.mol

Synonyms:Ag⁽¹⁺⁾*S₂C(CH₃C₆H₄)NCHN(C₆H₄CH₃)^(1-)=[Ag(S₂C(CH₃C₆H₄)NCHNC₆H₄CH₃)]

Chemical Property of Ag⁽¹⁺⁾*S₂C(CH₃C₆H₄)NCHN(C₆H₄CH₃)^(1-)=[Ag(S₂C(CH₃C₆H₄)NCHNC₆H₄CH₃)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ag⁽¹⁺⁾*S₂C(CH₃C₆H₄)NCHN(C₆H₄CH₃)^(1-)=[Ag(S₂C(CH₃C₆H₄)NCHNC₆H₄CH₃)]

There total 1 articles about Ag⁽¹⁺⁾*S₂C(CH₃C₆H₄)NCHN(C₆H₄CH₃)^(1-)=[Ag(S₂C(CH₃C₆H₄)NCHNC₆H₄CH₃)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

silver derivative of N,N'-di-p-tolylformamidine (65585-77-5) → Ag(1+)*S2C(CH3C6H4)NCHN(C6H4CH3)(1-)=[Ag(S2C(CH3C6H4)NCHNC6H4CH3)] (116722-41-9)

Guidance literature:

With carbon disulfide; In dichloromethane; CS2 added to soln. of (Ag(TolNCHNTol))n in CH2Cl2, stirred for 3 h; evapd., EtOH added, solid filtered off, washed with EtOH; elem. anal.;

DOI:10.1016/0022-328X(87)80102-X

Reference yield: 90.0%

(NBu4)2{palladium(μ-Br)bis(pentafluorophenyl)}2 (74436-10-5) + Ag(1+)*S2C(CH3C6H4)NCHN(C6H4CH3)(1-)=[Ag(S2C(CH3C6H4)NCHNC6H4CH3)] (116722-41-9) → N(C4H9)4(1+)*[Pd(C6F5)2(S2CN(C6H4CH3)CHNC6H4CH3)](1-)=[N(C4H9)4][Pd(C6F5)2(S2CN(C6H4CH3)CHNC6H4CH3)] (116722-40-8)

Guidance literature:

In dichloromethane; byproducts: AgBr; soln. of (NBu4)2(Pd2Br2(C6F5)4) in CH2Cl2 stirred with (Ag(S2CN(Tol)CHNTol))n for 15 h; AgBr filtered off, evapd., EtOH added, crystals filtered off, washed with cold EtOH; elem. anal.;

DOI:10.1016/0022-328X(87)80102-X

upstream raw materials:

silver derivative of N,N'-di-p-tolylformamidine

Downstream raw materials:

N(C₄H₉)4⁽¹⁺⁾*[Pd(C₆F₅)2(S₂CN(C₆H₄CH₃)CHNC₆H₄CH₃)]^(1-)=[N(C₄H₉)4][Pd(C₆F₅)2(S₂CN(C₆H₄CH₃)CHNC₆H₄CH₃)]